Effect of Mn(x)O(y) Nanoparticles Stabilized with Methionine on Germination of Barley Seeds (Hordeum vulgare L.)

The aim of this research was to study the effect of Mn(x)O(y) nanoparticles stabilized with L-methionine on the morphofunctional characteristics of the barley (Hordeum vulgare L.) crop. Mn(x)O(y) nanoparticles stabilized with L-methionine were synthesized using potassium permanganate and L-methionine. We established that Mn(x)O(y) nanoparticles have a diameter of 15 to 30 nm. According to quantum chemical modeling and IR spectroscopy, it is shown that the interaction of Mn(x)O(y) nanoparticles with L-methionine occurs through the amino group. It is found that Mn(x)O(y) nanoparticles stabilized with L-methionine have positive effects on the roots and seedling length, as well as the seed germination energy. The effect of Mn(x)O(y) nanoparticles on Hordeum vulgare L. seeds is nonlinear. At a concentration of 0.05 mg/mL, there was a statistically significant increase in the length of seedlings by 68% compared to the control group. We found that the root lengths of samples treated with Mn(x)O(y) nanoparticle sols with a concentration of 0.05 mg/mL were 62.8%, 32.7%, and 158.9% higher compared to samples treated with L-methionine, KMnO(4), and the control sample, respectively. We have shown that at a concentration of 0.05 mg/mL, the germination energy of seeds increases by 50.0% compared to the control sample, by 10.0% compared to the samples treated with L-methionine, and by 13.8% compared to the samples treated with KMnO(4).