Over Two-Fold Photoluminescence Enhancement from Single-Walled Carbon Nanotubes Induced by Oxygen Doping

Covalent functionalization of single-walled carbon nanotubes (SWCNTs) is a promising way to improve their photoluminescent (PL) brightness and thus make them applicable as a base material for infrared light emitters. We report as high as over two-fold enhancement of the SWCNT PL brightness by using...

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Autores principales: Eremin, Timofei, Eremina, Valentina, Svirko, Yuri, Obraztsov, Petr
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10180646/
https://www.ncbi.nlm.nih.gov/pubmed/37177106
http://dx.doi.org/10.3390/nano13091561
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author Eremin, Timofei
Eremina, Valentina
Svirko, Yuri
Obraztsov, Petr
author_facet Eremin, Timofei
Eremina, Valentina
Svirko, Yuri
Obraztsov, Petr
author_sort Eremin, Timofei
collection PubMed
description Covalent functionalization of single-walled carbon nanotubes (SWCNTs) is a promising way to improve their photoluminescent (PL) brightness and thus make them applicable as a base material for infrared light emitters. We report as high as over two-fold enhancement of the SWCNT PL brightness by using oxygen doping via the UV photodissociation of hypochlorite ions. By analyzing the temporal evolution of the PL and Raman spectra of SWCNTs in the course of the doping process, we conclude that the enhancement of SWCNTs PL brightness depends on the homogeneity of induced quantum defects distribution over the SWCNT surface.
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spelling pubmed-101806462023-05-13 Over Two-Fold Photoluminescence Enhancement from Single-Walled Carbon Nanotubes Induced by Oxygen Doping Eremin, Timofei Eremina, Valentina Svirko, Yuri Obraztsov, Petr Nanomaterials (Basel) Article Covalent functionalization of single-walled carbon nanotubes (SWCNTs) is a promising way to improve their photoluminescent (PL) brightness and thus make them applicable as a base material for infrared light emitters. We report as high as over two-fold enhancement of the SWCNT PL brightness by using oxygen doping via the UV photodissociation of hypochlorite ions. By analyzing the temporal evolution of the PL and Raman spectra of SWCNTs in the course of the doping process, we conclude that the enhancement of SWCNTs PL brightness depends on the homogeneity of induced quantum defects distribution over the SWCNT surface. MDPI 2023-05-06 /pmc/articles/PMC10180646/ /pubmed/37177106 http://dx.doi.org/10.3390/nano13091561 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Eremin, Timofei
Eremina, Valentina
Svirko, Yuri
Obraztsov, Petr
Over Two-Fold Photoluminescence Enhancement from Single-Walled Carbon Nanotubes Induced by Oxygen Doping
title Over Two-Fold Photoluminescence Enhancement from Single-Walled Carbon Nanotubes Induced by Oxygen Doping
title_full Over Two-Fold Photoluminescence Enhancement from Single-Walled Carbon Nanotubes Induced by Oxygen Doping
title_fullStr Over Two-Fold Photoluminescence Enhancement from Single-Walled Carbon Nanotubes Induced by Oxygen Doping
title_full_unstemmed Over Two-Fold Photoluminescence Enhancement from Single-Walled Carbon Nanotubes Induced by Oxygen Doping
title_short Over Two-Fold Photoluminescence Enhancement from Single-Walled Carbon Nanotubes Induced by Oxygen Doping
title_sort over two-fold photoluminescence enhancement from single-walled carbon nanotubes induced by oxygen doping
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10180646/
https://www.ncbi.nlm.nih.gov/pubmed/37177106
http://dx.doi.org/10.3390/nano13091561
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AT svirkoyuri overtwofoldphotoluminescenceenhancementfromsinglewalledcarbonnanotubesinducedbyoxygendoping
AT obraztsovpetr overtwofoldphotoluminescenceenhancementfromsinglewalledcarbonnanotubesinducedbyoxygendoping

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