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Valorization of Pennisetum setaceum: From Invasive Plant to Fiber Reinforcement of Injected Composites

During the control campaigns of Pennisetum setaceum (invasive species widespread worldwide), the generated waste has accumulated in landfills. This study investigates its use to obtain P. setaceum fibers for their application as reinforcement of polymeric materials for injection molding, thus facili...

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Autores principales: Cabrera-García, Patricia, Marrero, María Dolores, Benítez, Antonio Nizardo, Paz, Rubén
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10181305/
https://www.ncbi.nlm.nih.gov/pubmed/37176835
http://dx.doi.org/10.3390/plants12091777
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author Cabrera-García, Patricia
Marrero, María Dolores
Benítez, Antonio Nizardo
Paz, Rubén
author_facet Cabrera-García, Patricia
Marrero, María Dolores
Benítez, Antonio Nizardo
Paz, Rubén
author_sort Cabrera-García, Patricia
collection PubMed
description During the control campaigns of Pennisetum setaceum (invasive species widespread worldwide), the generated waste has accumulated in landfills. This study investigates its use to obtain P. setaceum fibers for their application as reinforcement of polymeric materials for injection molding, thus facilitating and promoting alternatives for the long-term sustainable management of P. setaceum. The extracted fibers were treated with alkaline, silane, acetic acid, and combined alkaline and silane treatments. Different composites with 20 and 40 wt% of fiber were extruded, and test samples were obtained by injection molding using recycled polyethylene as matrix. The composition of the fibers was determined by gravimetric methods, and contrasted with the analysis of the functional chemical groups using Fourier Transform Infrared Spectroscopy. Increases of up to 47% in the cellulose content of the treated fiber were observed. The thermal degradation was also evaluated using thermogravimetric analysis, which determined an increase in the degradation temperature, from 194 to 230 °C, after the combined alkaline–silane treatment. In order to analyze the differences in the composites, tensile, flexural, and impact properties were evaluated; in addition, differential scanning calorimetry was performed. Regarding the flexural behavior, it was possible to improve the flexural modulus up to 276% compared with that of the unreinforced polymer.
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spelling pubmed-101813052023-05-13 Valorization of Pennisetum setaceum: From Invasive Plant to Fiber Reinforcement of Injected Composites Cabrera-García, Patricia Marrero, María Dolores Benítez, Antonio Nizardo Paz, Rubén Plants (Basel) Article During the control campaigns of Pennisetum setaceum (invasive species widespread worldwide), the generated waste has accumulated in landfills. This study investigates its use to obtain P. setaceum fibers for their application as reinforcement of polymeric materials for injection molding, thus facilitating and promoting alternatives for the long-term sustainable management of P. setaceum. The extracted fibers were treated with alkaline, silane, acetic acid, and combined alkaline and silane treatments. Different composites with 20 and 40 wt% of fiber were extruded, and test samples were obtained by injection molding using recycled polyethylene as matrix. The composition of the fibers was determined by gravimetric methods, and contrasted with the analysis of the functional chemical groups using Fourier Transform Infrared Spectroscopy. Increases of up to 47% in the cellulose content of the treated fiber were observed. The thermal degradation was also evaluated using thermogravimetric analysis, which determined an increase in the degradation temperature, from 194 to 230 °C, after the combined alkaline–silane treatment. In order to analyze the differences in the composites, tensile, flexural, and impact properties were evaluated; in addition, differential scanning calorimetry was performed. Regarding the flexural behavior, it was possible to improve the flexural modulus up to 276% compared with that of the unreinforced polymer. MDPI 2023-04-26 /pmc/articles/PMC10181305/ /pubmed/37176835 http://dx.doi.org/10.3390/plants12091777 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Cabrera-García, Patricia
Marrero, María Dolores
Benítez, Antonio Nizardo
Paz, Rubén
Valorization of Pennisetum setaceum: From Invasive Plant to Fiber Reinforcement of Injected Composites
title Valorization of Pennisetum setaceum: From Invasive Plant to Fiber Reinforcement of Injected Composites
title_full Valorization of Pennisetum setaceum: From Invasive Plant to Fiber Reinforcement of Injected Composites
title_fullStr Valorization of Pennisetum setaceum: From Invasive Plant to Fiber Reinforcement of Injected Composites
title_full_unstemmed Valorization of Pennisetum setaceum: From Invasive Plant to Fiber Reinforcement of Injected Composites
title_short Valorization of Pennisetum setaceum: From Invasive Plant to Fiber Reinforcement of Injected Composites
title_sort valorization of pennisetum setaceum: from invasive plant to fiber reinforcement of injected composites
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10181305/
https://www.ncbi.nlm.nih.gov/pubmed/37176835
http://dx.doi.org/10.3390/plants12091777
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