Conformational, Host, and Vibrational Effects Giving Rise to Dynamic TADF Behavior in the Through-Space Charge Transfer, Triptycene Bridged Acridine-Triazine Donor Acceptor TADF Molecule TpAT-tFFO

[Image: see text] We present a joint experimental and theoretical study of the through-space charge transfer (CT) TADF molecule TpAT-tFFO. The measured fluorescence has a singular Gaussian line shape but two decay components, coming from two distinct molecular CT conformers, energetically only 20 me...

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Detalles Bibliográficos
Autores principales: Miranda-Salinas, Hector, Rodriguez-Serrano, Angela, Kaminski, Jeremy M., Dinkelbach, Fabian, Hiromichi, Nakagawa, Kusakabe, Yu, Kaji, Hironori, Marian, Christel M., Monkman, Andrew P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10184167/
https://www.ncbi.nlm.nih.gov/pubmed/37197385
http://dx.doi.org/10.1021/acs.jpcc.2c07529

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