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Distribution of Metallic Elements in Four Group Components of High-Temperature Coal Tar Pitch
[Image: see text] The metallic elements in high-temperature coal tar pitch (HCTP) will affect the properties of carbon materials produced from the HCTP. The study on the metallic elements in HCTP is essential for the quality improvement of its derived carbon materials. In this paper, the content of...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10193538/ https://www.ncbi.nlm.nih.gov/pubmed/37214714 http://dx.doi.org/10.1021/acsomega.2c06981 |
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author | Cheng, Weijie Guo, Shaoqing Sun, Zhengxuan Wei, Xian-xian Gao, Libing Cao, Yanzhi |
author_facet | Cheng, Weijie Guo, Shaoqing Sun, Zhengxuan Wei, Xian-xian Gao, Libing Cao, Yanzhi |
author_sort | Cheng, Weijie |
collection | PubMed |
description | [Image: see text] The metallic elements in high-temperature coal tar pitch (HCTP) will affect the properties of carbon materials produced from the HCTP. The study on the metallic elements in HCTP is essential for the quality improvement of its derived carbon materials. In this paper, the content of 15 metallic elements in HCTP and its four group components, including n-heptane-soluble substance (HS), n-heptane-insoluble–toluene-soluble substance (HI-TS), toluene-insoluble–quinoline-soluble substance (TI-QS), and quinoline-insoluble substance (QI), was determined. The results show that the content of Na, Ca, Fe, Mg, Zn, K, Pb, and Al is more than 100 ppm and is much higher than that of other metallic elements. The content of Ni, V, Cr, Mo, Sb, Cu, and Mn ranges from 0 to 50 ppm. By mass calculation of the contents of four group components in HCTP, it can be concluded that Na and Fe are randomly distributed in the group components. Al, Zn, Pb, V, and Mn are mainly distributed in the inorganic form in the QI component. Ca, Mg, K, Ni, Cr, Mo, Sb, and Cu are mainly distributed in the small molecular group components such as HS and HI-TS. |
format | Online Article Text |
id | pubmed-10193538 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-101935382023-05-19 Distribution of Metallic Elements in Four Group Components of High-Temperature Coal Tar Pitch Cheng, Weijie Guo, Shaoqing Sun, Zhengxuan Wei, Xian-xian Gao, Libing Cao, Yanzhi ACS Omega [Image: see text] The metallic elements in high-temperature coal tar pitch (HCTP) will affect the properties of carbon materials produced from the HCTP. The study on the metallic elements in HCTP is essential for the quality improvement of its derived carbon materials. In this paper, the content of 15 metallic elements in HCTP and its four group components, including n-heptane-soluble substance (HS), n-heptane-insoluble–toluene-soluble substance (HI-TS), toluene-insoluble–quinoline-soluble substance (TI-QS), and quinoline-insoluble substance (QI), was determined. The results show that the content of Na, Ca, Fe, Mg, Zn, K, Pb, and Al is more than 100 ppm and is much higher than that of other metallic elements. The content of Ni, V, Cr, Mo, Sb, Cu, and Mn ranges from 0 to 50 ppm. By mass calculation of the contents of four group components in HCTP, it can be concluded that Na and Fe are randomly distributed in the group components. Al, Zn, Pb, V, and Mn are mainly distributed in the inorganic form in the QI component. Ca, Mg, K, Ni, Cr, Mo, Sb, and Cu are mainly distributed in the small molecular group components such as HS and HI-TS. American Chemical Society 2023-05-01 /pmc/articles/PMC10193538/ /pubmed/37214714 http://dx.doi.org/10.1021/acsomega.2c06981 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Cheng, Weijie Guo, Shaoqing Sun, Zhengxuan Wei, Xian-xian Gao, Libing Cao, Yanzhi Distribution of Metallic Elements in Four Group Components of High-Temperature Coal Tar Pitch |
title | Distribution of
Metallic Elements in Four Group Components
of High-Temperature Coal Tar Pitch |
title_full | Distribution of
Metallic Elements in Four Group Components
of High-Temperature Coal Tar Pitch |
title_fullStr | Distribution of
Metallic Elements in Four Group Components
of High-Temperature Coal Tar Pitch |
title_full_unstemmed | Distribution of
Metallic Elements in Four Group Components
of High-Temperature Coal Tar Pitch |
title_short | Distribution of
Metallic Elements in Four Group Components
of High-Temperature Coal Tar Pitch |
title_sort | distribution of
metallic elements in four group components
of high-temperature coal tar pitch |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10193538/ https://www.ncbi.nlm.nih.gov/pubmed/37214714 http://dx.doi.org/10.1021/acsomega.2c06981 |
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