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Distribution of Metallic Elements in Four Group Components of High-Temperature Coal Tar Pitch

[Image: see text] The metallic elements in high-temperature coal tar pitch (HCTP) will affect the properties of carbon materials produced from the HCTP. The study on the metallic elements in HCTP is essential for the quality improvement of its derived carbon materials. In this paper, the content of...

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Autores principales: Cheng, Weijie, Guo, Shaoqing, Sun, Zhengxuan, Wei, Xian-xian, Gao, Libing, Cao, Yanzhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10193538/
https://www.ncbi.nlm.nih.gov/pubmed/37214714
http://dx.doi.org/10.1021/acsomega.2c06981
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author Cheng, Weijie
Guo, Shaoqing
Sun, Zhengxuan
Wei, Xian-xian
Gao, Libing
Cao, Yanzhi
author_facet Cheng, Weijie
Guo, Shaoqing
Sun, Zhengxuan
Wei, Xian-xian
Gao, Libing
Cao, Yanzhi
author_sort Cheng, Weijie
collection PubMed
description [Image: see text] The metallic elements in high-temperature coal tar pitch (HCTP) will affect the properties of carbon materials produced from the HCTP. The study on the metallic elements in HCTP is essential for the quality improvement of its derived carbon materials. In this paper, the content of 15 metallic elements in HCTP and its four group components, including n-heptane-soluble substance (HS), n-heptane-insoluble–toluene-soluble substance (HI-TS), toluene-insoluble–quinoline-soluble substance (TI-QS), and quinoline-insoluble substance (QI), was determined. The results show that the content of Na, Ca, Fe, Mg, Zn, K, Pb, and Al is more than 100 ppm and is much higher than that of other metallic elements. The content of Ni, V, Cr, Mo, Sb, Cu, and Mn ranges from 0 to 50 ppm. By mass calculation of the contents of four group components in HCTP, it can be concluded that Na and Fe are randomly distributed in the group components. Al, Zn, Pb, V, and Mn are mainly distributed in the inorganic form in the QI component. Ca, Mg, K, Ni, Cr, Mo, Sb, and Cu are mainly distributed in the small molecular group components such as HS and HI-TS.
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spelling pubmed-101935382023-05-19 Distribution of Metallic Elements in Four Group Components of High-Temperature Coal Tar Pitch Cheng, Weijie Guo, Shaoqing Sun, Zhengxuan Wei, Xian-xian Gao, Libing Cao, Yanzhi ACS Omega [Image: see text] The metallic elements in high-temperature coal tar pitch (HCTP) will affect the properties of carbon materials produced from the HCTP. The study on the metallic elements in HCTP is essential for the quality improvement of its derived carbon materials. In this paper, the content of 15 metallic elements in HCTP and its four group components, including n-heptane-soluble substance (HS), n-heptane-insoluble–toluene-soluble substance (HI-TS), toluene-insoluble–quinoline-soluble substance (TI-QS), and quinoline-insoluble substance (QI), was determined. The results show that the content of Na, Ca, Fe, Mg, Zn, K, Pb, and Al is more than 100 ppm and is much higher than that of other metallic elements. The content of Ni, V, Cr, Mo, Sb, Cu, and Mn ranges from 0 to 50 ppm. By mass calculation of the contents of four group components in HCTP, it can be concluded that Na and Fe are randomly distributed in the group components. Al, Zn, Pb, V, and Mn are mainly distributed in the inorganic form in the QI component. Ca, Mg, K, Ni, Cr, Mo, Sb, and Cu are mainly distributed in the small molecular group components such as HS and HI-TS. American Chemical Society 2023-05-01 /pmc/articles/PMC10193538/ /pubmed/37214714 http://dx.doi.org/10.1021/acsomega.2c06981 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Cheng, Weijie
Guo, Shaoqing
Sun, Zhengxuan
Wei, Xian-xian
Gao, Libing
Cao, Yanzhi
Distribution of Metallic Elements in Four Group Components of High-Temperature Coal Tar Pitch
title Distribution of Metallic Elements in Four Group Components of High-Temperature Coal Tar Pitch
title_full Distribution of Metallic Elements in Four Group Components of High-Temperature Coal Tar Pitch
title_fullStr Distribution of Metallic Elements in Four Group Components of High-Temperature Coal Tar Pitch
title_full_unstemmed Distribution of Metallic Elements in Four Group Components of High-Temperature Coal Tar Pitch
title_short Distribution of Metallic Elements in Four Group Components of High-Temperature Coal Tar Pitch
title_sort distribution of metallic elements in four group components of high-temperature coal tar pitch
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10193538/
https://www.ncbi.nlm.nih.gov/pubmed/37214714
http://dx.doi.org/10.1021/acsomega.2c06981
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