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Approaching enzymatic catalysis with zeolites or how to select one reaction mechanism competing with others

Approaching the level of molecular recognition of enzymes with solid catalysts is a challenging goal, achieved in this work for the competing transalkylation and disproportionation of diethylbenzene catalyzed by acid zeolites. The key diaryl intermediates for the two competing reactions only differ...

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Detalles Bibliográficos
Autores principales: Ferri, Pau, Li, Chengeng, Schwalbe-Koda, Daniel, Xie, Mingrou, Moliner, Manuel, Gómez-Bombarelli, Rafael, Boronat, Mercedes, Corma, Avelino
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10198988/
https://www.ncbi.nlm.nih.gov/pubmed/37208318
http://dx.doi.org/10.1038/s41467-023-38544-z

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