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Geochemical characterisation of clastic sediments in Kompina (N'kapa Formation, NW Douala Basin, West Cameroon): Implication for provenance, paleoweathering and sediment maturity

Chemical analyses were carried out on clastic sedimentary rocks in Kompina (N'kapa Formation of the NW, Douala Basin, West Africa) to disclosed the composition of their source rock, characterised their tectonic domains, decipher the intensity of the past weathering, sedimentary cycles and matur...

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Autores principales: Kwankam, Florence Njinto, Ekoko Eric, Bokanda, Adama, Amaya, Salomon Bertrant, Bisse, Njeck Rexon Junior, Anyeku, Shannon Ngwakfu, Nfor, Fidelis Esue, Mokake, Hewett Ekumeli, Matombo, Maureen Ntube, Ngwane, Agyingi, M. Christopher
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10205521/
https://www.ncbi.nlm.nih.gov/pubmed/37234633
http://dx.doi.org/10.1016/j.heliyon.2023.e16034
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author Kwankam, Florence Njinto
Ekoko Eric, Bokanda
Adama, Amaya
Salomon Bertrant, Bisse
Njeck Rexon Junior, Anyeku
Shannon Ngwakfu, Nfor
Fidelis Esue, Mokake
Hewett Ekumeli, Matombo
Maureen Ntube, Ngwane
Agyingi, M. Christopher
author_facet Kwankam, Florence Njinto
Ekoko Eric, Bokanda
Adama, Amaya
Salomon Bertrant, Bisse
Njeck Rexon Junior, Anyeku
Shannon Ngwakfu, Nfor
Fidelis Esue, Mokake
Hewett Ekumeli, Matombo
Maureen Ntube, Ngwane
Agyingi, M. Christopher
author_sort Kwankam, Florence Njinto
collection PubMed
description Chemical analyses were carried out on clastic sedimentary rocks in Kompina (N'kapa Formation of the NW, Douala Basin, West Africa) to disclosed the composition of their source rock, characterised their tectonic domains, decipher the intensity of the past weathering, sedimentary cycles and maturity using concentrations of major oxides, REES and trace elements. Provenance diagram constructed from ratios of La/Co, La/Sc, Th/Sc, Cr/Th and from binary diagrams of Zr vs TiO(2) and AL(2)O(3)vs TiO(2), disclosed a felsic rock composition as the source rock of the Kompina clastic rocks. The felsic source rock composition designated for the studied clastic materials is also supported by LREE enrichment over HREE and a negative europium anomaly on chondrite calculation and diagram. New discriminant functions diagrams to delineate between active and passive domains such as DF 1&2(Arc-Rift-Col)(M1), DF1&2(Arc-Rift-Col)(M2) combined with diagrams of DF(A-P)M, DF(A-P)MT label a passive tectonic setting characteristics for the source rock where there studied clastic materials were sorted. The weathering intensity and plagioclase lixiviation revealed by the CIA and PIA indexes advocate a weak to intense strength of chemical weathering and lixiviation of plagioclase felspars while the CIX and PIX with elimination of CaO in their formulars show extreme intensity of weathering and lixiviation of plagioclase felspars. Most of the samples show immature nature from their ICV values > 1 but with the introduction of ICV(new) in this work, where oxides of iron and calcite are considered as cement and eliminated from the formular show that all the studied samples have values < 1 indicating they are mature. Plotted diagrams of Th/Sc, and (Gd/Yb)(N) ratios, with relationship of Zr and (La/Yb)N shows that the studied clastic materials are mature, second cycle sediments, which have experience zircon mineral addition.
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spelling pubmed-102055212023-05-25 Geochemical characterisation of clastic sediments in Kompina (N'kapa Formation, NW Douala Basin, West Cameroon): Implication for provenance, paleoweathering and sediment maturity Kwankam, Florence Njinto Ekoko Eric, Bokanda Adama, Amaya Salomon Bertrant, Bisse Njeck Rexon Junior, Anyeku Shannon Ngwakfu, Nfor Fidelis Esue, Mokake Hewett Ekumeli, Matombo Maureen Ntube, Ngwane Agyingi, M. Christopher Heliyon Research Article Chemical analyses were carried out on clastic sedimentary rocks in Kompina (N'kapa Formation of the NW, Douala Basin, West Africa) to disclosed the composition of their source rock, characterised their tectonic domains, decipher the intensity of the past weathering, sedimentary cycles and maturity using concentrations of major oxides, REES and trace elements. Provenance diagram constructed from ratios of La/Co, La/Sc, Th/Sc, Cr/Th and from binary diagrams of Zr vs TiO(2) and AL(2)O(3)vs TiO(2), disclosed a felsic rock composition as the source rock of the Kompina clastic rocks. The felsic source rock composition designated for the studied clastic materials is also supported by LREE enrichment over HREE and a negative europium anomaly on chondrite calculation and diagram. New discriminant functions diagrams to delineate between active and passive domains such as DF 1&2(Arc-Rift-Col)(M1), DF1&2(Arc-Rift-Col)(M2) combined with diagrams of DF(A-P)M, DF(A-P)MT label a passive tectonic setting characteristics for the source rock where there studied clastic materials were sorted. The weathering intensity and plagioclase lixiviation revealed by the CIA and PIA indexes advocate a weak to intense strength of chemical weathering and lixiviation of plagioclase felspars while the CIX and PIX with elimination of CaO in their formulars show extreme intensity of weathering and lixiviation of plagioclase felspars. Most of the samples show immature nature from their ICV values > 1 but with the introduction of ICV(new) in this work, where oxides of iron and calcite are considered as cement and eliminated from the formular show that all the studied samples have values < 1 indicating they are mature. Plotted diagrams of Th/Sc, and (Gd/Yb)(N) ratios, with relationship of Zr and (La/Yb)N shows that the studied clastic materials are mature, second cycle sediments, which have experience zircon mineral addition. Elsevier 2023-05-12 /pmc/articles/PMC10205521/ /pubmed/37234633 http://dx.doi.org/10.1016/j.heliyon.2023.e16034 Text en © 2023 The Authors https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Research Article
Kwankam, Florence Njinto
Ekoko Eric, Bokanda
Adama, Amaya
Salomon Bertrant, Bisse
Njeck Rexon Junior, Anyeku
Shannon Ngwakfu, Nfor
Fidelis Esue, Mokake
Hewett Ekumeli, Matombo
Maureen Ntube, Ngwane
Agyingi, M. Christopher
Geochemical characterisation of clastic sediments in Kompina (N'kapa Formation, NW Douala Basin, West Cameroon): Implication for provenance, paleoweathering and sediment maturity
title Geochemical characterisation of clastic sediments in Kompina (N'kapa Formation, NW Douala Basin, West Cameroon): Implication for provenance, paleoweathering and sediment maturity
title_full Geochemical characterisation of clastic sediments in Kompina (N'kapa Formation, NW Douala Basin, West Cameroon): Implication for provenance, paleoweathering and sediment maturity
title_fullStr Geochemical characterisation of clastic sediments in Kompina (N'kapa Formation, NW Douala Basin, West Cameroon): Implication for provenance, paleoweathering and sediment maturity
title_full_unstemmed Geochemical characterisation of clastic sediments in Kompina (N'kapa Formation, NW Douala Basin, West Cameroon): Implication for provenance, paleoweathering and sediment maturity
title_short Geochemical characterisation of clastic sediments in Kompina (N'kapa Formation, NW Douala Basin, West Cameroon): Implication for provenance, paleoweathering and sediment maturity
title_sort geochemical characterisation of clastic sediments in kompina (n'kapa formation, nw douala basin, west cameroon): implication for provenance, paleoweathering and sediment maturity
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10205521/
https://www.ncbi.nlm.nih.gov/pubmed/37234633
http://dx.doi.org/10.1016/j.heliyon.2023.e16034
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