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Redox Potentials of Uranyl Ions in Macrocyclic Complexes: Quantifying the Role of Counter-Ions
[Image: see text] Several uranyl ions strapped with Schiff-base ligands in the presence of redox-innocent metal ions are synthesized, and their reduction potentials are recently estimated. The change in Lewis acidity of the redox-innocent metal ions contributes to ∼60 mV/pK(a) unit quantified which...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10210231/ https://www.ncbi.nlm.nih.gov/pubmed/37251172 http://dx.doi.org/10.1021/acsomega.3c01244 |