Cargando…
Vitamin B(12) and hydrogen atom transfer cooperative catalysis as a hydride nucleophile mimic in epoxide ring opening
Epoxide ring-opening reactions have long been utilized to furnish alcohol products that are valuable in many subfields of chemistry. While many epoxide-opening reactions are known, the hydrogenative opening of epoxides via ionic means remains challenging because of harsh conditions and reactive hydr...
Autores principales: | Funk, Brian E., Pauze, Martin, Lu, Yen-Chu, Moser, Austin J., Wolf, Gemma, West, Julian G. |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10210593/ https://www.ncbi.nlm.nih.gov/pubmed/37235063 http://dx.doi.org/10.1016/j.xcrp.2023.101372 |
Ejemplares similares
-
Biocatalytic Aromaticity-Breaking Epoxidation of Naphthalene
and Nucleophilic Ring-Opening Reactions
por: Zhang, Wuyuan, et al.
Publicado: (2021) -
The design of organic catalysis for epoxidation by hydrogen peroxide
por: Alder, Roger W., et al.
Publicado: (2005) -
Resolving hydrogen atoms at metal-metal hydride interfaces
por: de Graaf, Sytze, et al.
Publicado: (2020) -
G‐type Halohydrin Dehalogenases Catalyze Ring Opening Reactions of Cyclic Epoxides with Diverse Anionic Nucleophiles
por: Solarczek, Jennifer, et al.
Publicado: (2022) -
Vibrational characterization of a diiron bridging hydride complex – a model for hydrogen catalysis
por: Gee, Leland B., et al.
Publicado: (2020)