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The Fully Oxidized State of the Glutamate Coordinated O(2)-Tolerant [NiFe]-Hydrogenase Shows a Ni(III)/Fe(III) Open-Shell Singlet Ground State
[Image: see text] The oxygen tolerance of the [NiFe]-hydrogenase from H. thermoluteolus was recently assigned to originate from an unusual coordination sphere of the active site nickel atom (Shomura et al. Science2017, 357, 928–932, 10.1126/science.aan4497). In the oxidized state, a terminal cystein...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10214449/ https://www.ncbi.nlm.nih.gov/pubmed/37159341 http://dx.doi.org/10.1021/jacs.3c02438 |