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Interaction of Ions in Organic and Aqueous Media with an Ion-Pair Sensor Equipped with a BODIPY Reporter: An ON1-OFF-ON2-ON3 Fluorescent Assay
Here, we present a ditopic ion-pair sensor, B1, containing the BODIPY reporter unit in its structure, which is shown to be able—thanks to the presence of two heterogeneous binding domains—to interact with anions in an enhanced manner in the presence of cations. This enables it to interact with salts...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10218023/ https://www.ncbi.nlm.nih.gov/pubmed/37239885 http://dx.doi.org/10.3390/ijms24108536 |
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author | Zaleskaya-Hernik, Marta Dobrzycki, Łukasz Romański, Jan |
author_facet | Zaleskaya-Hernik, Marta Dobrzycki, Łukasz Romański, Jan |
author_sort | Zaleskaya-Hernik, Marta |
collection | PubMed |
description | Here, we present a ditopic ion-pair sensor, B1, containing the BODIPY reporter unit in its structure, which is shown to be able—thanks to the presence of two heterogeneous binding domains—to interact with anions in an enhanced manner in the presence of cations. This enables it to interact with salts even in 99% aqueous solutions, making B1 a good candidate in terms of visual salt detection in the aquatic environment. Receptor B1’s ability to extract and release salt was applied in the transport of potassium chloride through a bulk liquid membrane. Working with a concentration of B1 in the organic phase and with the presence of a specific salt in an aqueous solution, an inverted transport experiment was also demonstrated. By varying the type and the amount of the anions added to B1, we were able to develop diverse optical responses, including a unique four-step ON1-OFF-ON2-ON3 output. |
format | Online Article Text |
id | pubmed-10218023 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-102180232023-05-27 Interaction of Ions in Organic and Aqueous Media with an Ion-Pair Sensor Equipped with a BODIPY Reporter: An ON1-OFF-ON2-ON3 Fluorescent Assay Zaleskaya-Hernik, Marta Dobrzycki, Łukasz Romański, Jan Int J Mol Sci Article Here, we present a ditopic ion-pair sensor, B1, containing the BODIPY reporter unit in its structure, which is shown to be able—thanks to the presence of two heterogeneous binding domains—to interact with anions in an enhanced manner in the presence of cations. This enables it to interact with salts even in 99% aqueous solutions, making B1 a good candidate in terms of visual salt detection in the aquatic environment. Receptor B1’s ability to extract and release salt was applied in the transport of potassium chloride through a bulk liquid membrane. Working with a concentration of B1 in the organic phase and with the presence of a specific salt in an aqueous solution, an inverted transport experiment was also demonstrated. By varying the type and the amount of the anions added to B1, we were able to develop diverse optical responses, including a unique four-step ON1-OFF-ON2-ON3 output. MDPI 2023-05-10 /pmc/articles/PMC10218023/ /pubmed/37239885 http://dx.doi.org/10.3390/ijms24108536 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Zaleskaya-Hernik, Marta Dobrzycki, Łukasz Romański, Jan Interaction of Ions in Organic and Aqueous Media with an Ion-Pair Sensor Equipped with a BODIPY Reporter: An ON1-OFF-ON2-ON3 Fluorescent Assay |
title | Interaction of Ions in Organic and Aqueous Media with an Ion-Pair Sensor Equipped with a BODIPY Reporter: An ON1-OFF-ON2-ON3 Fluorescent Assay |
title_full | Interaction of Ions in Organic and Aqueous Media with an Ion-Pair Sensor Equipped with a BODIPY Reporter: An ON1-OFF-ON2-ON3 Fluorescent Assay |
title_fullStr | Interaction of Ions in Organic and Aqueous Media with an Ion-Pair Sensor Equipped with a BODIPY Reporter: An ON1-OFF-ON2-ON3 Fluorescent Assay |
title_full_unstemmed | Interaction of Ions in Organic and Aqueous Media with an Ion-Pair Sensor Equipped with a BODIPY Reporter: An ON1-OFF-ON2-ON3 Fluorescent Assay |
title_short | Interaction of Ions in Organic and Aqueous Media with an Ion-Pair Sensor Equipped with a BODIPY Reporter: An ON1-OFF-ON2-ON3 Fluorescent Assay |
title_sort | interaction of ions in organic and aqueous media with an ion-pair sensor equipped with a bodipy reporter: an on1-off-on2-on3 fluorescent assay |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10218023/ https://www.ncbi.nlm.nih.gov/pubmed/37239885 http://dx.doi.org/10.3390/ijms24108536 |
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