Visible Light-Mediated Organoboron-Catalyzed Metal-Free Synthesis of Silanols from Silanes

Herein, a four-coordinated organoboron compound, aminoquinoline diarylboron (AQDAB), is utilized as the photocatalyst in the oxidation of silane to silanol. This strategy effectively oxidizes Si–H bonds, affording Si–O bonds. Generally, the corresponding silanols can be obtained in moderate to good...

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Autores principales: Yang, Jinbo, Cao, Xiangxue, Wei, Lanfeng, Zhang, Jianshu, Zhang, Jinli, Liu, Ping, Xu, Liang, Li, Pengfei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10222655/
https://www.ncbi.nlm.nih.gov/pubmed/37241823
http://dx.doi.org/10.3390/molecules28104082
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author Yang, Jinbo
Cao, Xiangxue
Wei, Lanfeng
Zhang, Jianshu
Zhang, Jinli
Liu, Ping
Xu, Liang
Li, Pengfei
author_facet Yang, Jinbo
Cao, Xiangxue
Wei, Lanfeng
Zhang, Jianshu
Zhang, Jinli
Liu, Ping
Xu, Liang
Li, Pengfei
author_sort Yang, Jinbo
collection PubMed
description Herein, a four-coordinated organoboron compound, aminoquinoline diarylboron (AQDAB), is utilized as the photocatalyst in the oxidation of silane to silanol. This strategy effectively oxidizes Si–H bonds, affording Si–O bonds. Generally, the corresponding silanols can be obtained in moderate to good yields at room temperature under oxygen atmospheres, representing a green protocol to complement the existing preparation methods for silanols.
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spelling pubmed-102226552023-05-28 Visible Light-Mediated Organoboron-Catalyzed Metal-Free Synthesis of Silanols from Silanes Yang, Jinbo Cao, Xiangxue Wei, Lanfeng Zhang, Jianshu Zhang, Jinli Liu, Ping Xu, Liang Li, Pengfei Molecules Article Herein, a four-coordinated organoboron compound, aminoquinoline diarylboron (AQDAB), is utilized as the photocatalyst in the oxidation of silane to silanol. This strategy effectively oxidizes Si–H bonds, affording Si–O bonds. Generally, the corresponding silanols can be obtained in moderate to good yields at room temperature under oxygen atmospheres, representing a green protocol to complement the existing preparation methods for silanols. MDPI 2023-05-13 /pmc/articles/PMC10222655/ /pubmed/37241823 http://dx.doi.org/10.3390/molecules28104082 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Yang, Jinbo
Cao, Xiangxue
Wei, Lanfeng
Zhang, Jianshu
Zhang, Jinli
Liu, Ping
Xu, Liang
Li, Pengfei
Visible Light-Mediated Organoboron-Catalyzed Metal-Free Synthesis of Silanols from Silanes
title Visible Light-Mediated Organoboron-Catalyzed Metal-Free Synthesis of Silanols from Silanes
title_full Visible Light-Mediated Organoboron-Catalyzed Metal-Free Synthesis of Silanols from Silanes
title_fullStr Visible Light-Mediated Organoboron-Catalyzed Metal-Free Synthesis of Silanols from Silanes
title_full_unstemmed Visible Light-Mediated Organoboron-Catalyzed Metal-Free Synthesis of Silanols from Silanes
title_short Visible Light-Mediated Organoboron-Catalyzed Metal-Free Synthesis of Silanols from Silanes
title_sort visible light-mediated organoboron-catalyzed metal-free synthesis of silanols from silanes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10222655/
https://www.ncbi.nlm.nih.gov/pubmed/37241823
http://dx.doi.org/10.3390/molecules28104082
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