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Visible Light-Mediated Organoboron-Catalyzed Metal-Free Synthesis of Silanols from Silanes

Herein, a four-coordinated organoboron compound, aminoquinoline diarylboron (AQDAB), is utilized as the photocatalyst in the oxidation of silane to silanol. This strategy effectively oxidizes Si–H bonds, affording Si–O bonds. Generally, the corresponding silanols can be obtained in moderate to good...

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Detalles Bibliográficos
Autores principales: Yang, Jinbo, Cao, Xiangxue, Wei, Lanfeng, Zhang, Jianshu, Zhang, Jinli, Liu, Ping, Xu, Liang, Li, Pengfei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10222655/
https://www.ncbi.nlm.nih.gov/pubmed/37241823
http://dx.doi.org/10.3390/molecules28104082

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