Analogy of the Reactions of Aromatic and Aliphatic π-Electrophiles with Nucleophiles

The aim of this essay is to disclose the similarity of a great variety of reactions that proceed between nucleophiles and π-electrophiles—both aromatic and aliphatic. These reactions proceed via initial reversible addition, followed by a variety of transformations that are common for the adducts of...

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Detalles Bibliográficos
Autores principales: Barbasiewicz, Michał, Fedoryński, Michał, Loska, Rafał, Mąkosza, Mieczysław
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10223524/
https://www.ncbi.nlm.nih.gov/pubmed/37241756
http://dx.doi.org/10.3390/molecules28104015
Descripción
Sumario:The aim of this essay is to disclose the similarity of a great variety of reactions that proceed between nucleophiles and π-electrophiles—both aromatic and aliphatic. These reactions proceed via initial reversible addition, followed by a variety of transformations that are common for the adducts of both aliphatic and aromatic electrophiles. We hope that understanding of this analogy should help to expand the scope of the known reactions and inspire the search for new reactions that were overlooked.

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