Ru-Controlled Thymine Tautomerization Frozen by a k(1)(O)-, k(2)(N,O)-Metallacycle: An Experimental and Theoretical Approach

The reaction of mer-(Ru(H)(2)(CO)(PPh(3))(3)) (1) with one equivalent of thymine acetic acid (THAcH) unexpectedly produces the macrocyclic dimer k(1)(O), k(2)(N,O)-(Ru(CO)(PPh(3))(2)THAc)(2) (4) and, concomitantly, the doubly coordinated species k(1)(O), k(2)(O,O)-(Ru(CO)(PPh(3))(2)THAc) (5). The re...

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Detalles Bibliográficos
Autores principales: Bordoni, Silvia, Tarroni, Riccardo, Monari, Magda, Cerini, Stefano, Battaglia, Fabio, Micheletti, Gabriele, Boga, Carla, Drius, Giacomo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10223689/
https://www.ncbi.nlm.nih.gov/pubmed/37241724
http://dx.doi.org/10.3390/molecules28103983

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