Construction of Self-Assembly Based Tunable Absorber: Lightweight, Hydrophobic and Self-Cleaning Properties

Although multifunctional aerogels are expected to be used in applications such as portable electronic devices, it is still a great challenge to confer multifunctionality to aerogels while maintaining their inherent microstructure. Herein, a simple method is proposed to prepare multifunctional NiCo/C aerogels with excellent electromagnetic wave absorption properties, superhydrophobicity, and self-cleaning by water-induced NiCo-MOF self-assembly. Specifically, the impedance matching of the three-dimensional (3D) structure and the interfacial polarization provided by CoNi/C as well as the defect-induced dipole polarization are the primary contributors to the broadband absorption. As a result, the prepared NiCo/C aerogels have a broadband width of 6.22 GHz at 1.9 mm. Due to the presence of hydrophobic functional groups, CoNi/C aerogels improve the stability in humid environments and obtain hydrophobicity with large contact angles > 140°. This multifunctional aerogel has promising applications in electromagnetic wave absorption, resistance to water or humid environments. [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s40820-023-01108-3.