Cargando…
Colorimetric mercury detection with enhanced sensitivity using magnetic-Au hybrid nanoparticles
Due to the neural toxicity of mercury, there is a need for the development of on-site detection systems for Hg(2+) monitoring. To this end, a new colorimetric mercury detection probe, Fe(3)O(4)@SiO(2)@Au (magnetic-Au; Mag-Au) hybrid nanoparticles, has been developed. The Au on the surface of Mag-Au...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
RSC
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10228351/ https://www.ncbi.nlm.nih.gov/pubmed/37260498 http://dx.doi.org/10.1039/d3na00129f |
_version_ | 1785050945704427520 |
---|---|
author | Jeong, Miseon Bae, Dahyun Choi, Jin-sil |
author_facet | Jeong, Miseon Bae, Dahyun Choi, Jin-sil |
author_sort | Jeong, Miseon |
collection | PubMed |
description | Due to the neural toxicity of mercury, there is a need for the development of on-site detection systems for Hg(2+) monitoring. To this end, a new colorimetric mercury detection probe, Fe(3)O(4)@SiO(2)@Au (magnetic-Au; Mag-Au) hybrid nanoparticles, has been developed. The Au on the surface of Mag-Au is an indicator of Hg(2+), which forms an AuHg alloy (amalgam) on their surface (Mag-Au@Hg), with excellent peroxidase-like activity. The oxidation of 3,3′,5,5′-tetramethylbenzidine by Mag-Au@Hg resulted in a color change of the indicator solution, which was enhanced with increasing Hg(2+) concentration. Mag-Au can be used to detect Hg(2+) at nanomolar concentrations. Additionally, magnetic separation can be used to easily purify and concentrate the Mag-Au@Hg from samples, and thus avoid interference from unwanted residues or colored samples. The feasibility of Mag-Au for Hg(2+) detection was tested with an artificial urine solution and it can be used to detect Hg(2+) in various real samples, such as river water, seawater, food, and biological samples. |
format | Online Article Text |
id | pubmed-10228351 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | RSC |
record_format | MEDLINE/PubMed |
spelling | pubmed-102283512023-05-31 Colorimetric mercury detection with enhanced sensitivity using magnetic-Au hybrid nanoparticles Jeong, Miseon Bae, Dahyun Choi, Jin-sil Nanoscale Adv Chemistry Due to the neural toxicity of mercury, there is a need for the development of on-site detection systems for Hg(2+) monitoring. To this end, a new colorimetric mercury detection probe, Fe(3)O(4)@SiO(2)@Au (magnetic-Au; Mag-Au) hybrid nanoparticles, has been developed. The Au on the surface of Mag-Au is an indicator of Hg(2+), which forms an AuHg alloy (amalgam) on their surface (Mag-Au@Hg), with excellent peroxidase-like activity. The oxidation of 3,3′,5,5′-tetramethylbenzidine by Mag-Au@Hg resulted in a color change of the indicator solution, which was enhanced with increasing Hg(2+) concentration. Mag-Au can be used to detect Hg(2+) at nanomolar concentrations. Additionally, magnetic separation can be used to easily purify and concentrate the Mag-Au@Hg from samples, and thus avoid interference from unwanted residues or colored samples. The feasibility of Mag-Au for Hg(2+) detection was tested with an artificial urine solution and it can be used to detect Hg(2+) in various real samples, such as river water, seawater, food, and biological samples. RSC 2023-05-15 /pmc/articles/PMC10228351/ /pubmed/37260498 http://dx.doi.org/10.1039/d3na00129f Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Jeong, Miseon Bae, Dahyun Choi, Jin-sil Colorimetric mercury detection with enhanced sensitivity using magnetic-Au hybrid nanoparticles |
title | Colorimetric mercury detection with enhanced sensitivity using magnetic-Au hybrid nanoparticles |
title_full | Colorimetric mercury detection with enhanced sensitivity using magnetic-Au hybrid nanoparticles |
title_fullStr | Colorimetric mercury detection with enhanced sensitivity using magnetic-Au hybrid nanoparticles |
title_full_unstemmed | Colorimetric mercury detection with enhanced sensitivity using magnetic-Au hybrid nanoparticles |
title_short | Colorimetric mercury detection with enhanced sensitivity using magnetic-Au hybrid nanoparticles |
title_sort | colorimetric mercury detection with enhanced sensitivity using magnetic-au hybrid nanoparticles |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10228351/ https://www.ncbi.nlm.nih.gov/pubmed/37260498 http://dx.doi.org/10.1039/d3na00129f |
work_keys_str_mv | AT jeongmiseon colorimetricmercurydetectionwithenhancedsensitivityusingmagneticauhybridnanoparticles AT baedahyun colorimetricmercurydetectionwithenhancedsensitivityusingmagneticauhybridnanoparticles AT choijinsil colorimetricmercurydetectionwithenhancedsensitivityusingmagneticauhybridnanoparticles |