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Photothermal Catalytic CO(2) Conversion: Beyond Catalysis and Photocatalysis
In recent years, the combination of both thermal and photochemical contributions has provided interesting opportunities for solar upgrading of catalytic processes. Photothermal catalysis works at the interface between purely photochemical processes, which involve the direct conversion of photon ener...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer International Publishing
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10229455/ https://www.ncbi.nlm.nih.gov/pubmed/37253819 http://dx.doi.org/10.1007/s41061-023-00430-z |
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author | Fresno, Fernando Iglesias-Juez, Ana Coronado, Juan M. |
author_facet | Fresno, Fernando Iglesias-Juez, Ana Coronado, Juan M. |
author_sort | Fresno, Fernando |
collection | PubMed |
description | In recent years, the combination of both thermal and photochemical contributions has provided interesting opportunities for solar upgrading of catalytic processes. Photothermal catalysis works at the interface between purely photochemical processes, which involve the direct conversion of photon energy into chemical energy, and classical thermal catalysis, in which the catalyst is activated by temperature. Thus, photothermal catalysis acts in two different ways on the energy path of the reaction. This combined catalysis, of which the fundamental principles will be reviewed here, is particularly promising for the activation of small reactive molecules at moderate temperatures compared to thermal catalysis and with higher reaction rates than those attained in photocatalysis, and it has gained a great deal of attention in the last years. Among the different applications of photothermal catalysis, CO(2) conversion is probably the most studied, although reaction mechanisms and photonic-thermal synergy pathways are still quite unclear and, from the reaction route point of view, it can be said that photothermal-catalytic CO(2) reduction processes are still in their infancy. This article intends to provide an overview of the principles underpinning photothermal catalysis and its application to the conversion of CO(2) into useful molecules, with application essentially as fuels but also as chemical building blocks. The most relevant specific cases published to date will be also reviewed from the viewpoint of selectivity towards the most frequent target products. |
format | Online Article Text |
id | pubmed-10229455 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Springer International Publishing |
record_format | MEDLINE/PubMed |
spelling | pubmed-102294552023-06-01 Photothermal Catalytic CO(2) Conversion: Beyond Catalysis and Photocatalysis Fresno, Fernando Iglesias-Juez, Ana Coronado, Juan M. Top Curr Chem (Cham) Review In recent years, the combination of both thermal and photochemical contributions has provided interesting opportunities for solar upgrading of catalytic processes. Photothermal catalysis works at the interface between purely photochemical processes, which involve the direct conversion of photon energy into chemical energy, and classical thermal catalysis, in which the catalyst is activated by temperature. Thus, photothermal catalysis acts in two different ways on the energy path of the reaction. This combined catalysis, of which the fundamental principles will be reviewed here, is particularly promising for the activation of small reactive molecules at moderate temperatures compared to thermal catalysis and with higher reaction rates than those attained in photocatalysis, and it has gained a great deal of attention in the last years. Among the different applications of photothermal catalysis, CO(2) conversion is probably the most studied, although reaction mechanisms and photonic-thermal synergy pathways are still quite unclear and, from the reaction route point of view, it can be said that photothermal-catalytic CO(2) reduction processes are still in their infancy. This article intends to provide an overview of the principles underpinning photothermal catalysis and its application to the conversion of CO(2) into useful molecules, with application essentially as fuels but also as chemical building blocks. The most relevant specific cases published to date will be also reviewed from the viewpoint of selectivity towards the most frequent target products. Springer International Publishing 2023-05-30 2023 /pmc/articles/PMC10229455/ /pubmed/37253819 http://dx.doi.org/10.1007/s41061-023-00430-z Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
spellingShingle | Review Fresno, Fernando Iglesias-Juez, Ana Coronado, Juan M. Photothermal Catalytic CO(2) Conversion: Beyond Catalysis and Photocatalysis |
title | Photothermal Catalytic CO(2) Conversion: Beyond Catalysis and Photocatalysis |
title_full | Photothermal Catalytic CO(2) Conversion: Beyond Catalysis and Photocatalysis |
title_fullStr | Photothermal Catalytic CO(2) Conversion: Beyond Catalysis and Photocatalysis |
title_full_unstemmed | Photothermal Catalytic CO(2) Conversion: Beyond Catalysis and Photocatalysis |
title_short | Photothermal Catalytic CO(2) Conversion: Beyond Catalysis and Photocatalysis |
title_sort | photothermal catalytic co(2) conversion: beyond catalysis and photocatalysis |
topic | Review |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10229455/ https://www.ncbi.nlm.nih.gov/pubmed/37253819 http://dx.doi.org/10.1007/s41061-023-00430-z |
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