Cargando…

Semiconducting MOFs on ultraviolet laser-induced graphene with a hierarchical pore architecture for NO(2) monitoring

Due to rapid urbanization worldwide, monitoring the concentration of nitrogen dioxide (NO(2)), which causes cardiovascular and respiratory diseases, has attracted considerable attention. Developing real-time sensors to detect parts-per-billion (ppb)-level NO(2) remains challenging due to limited sen...

Descripción completa

Detalles Bibliográficos
Autores principales: Lim, Hyeongtae, Kwon, Hyeokjin, Kang, Hongki, Jang, Jae Eun, Kwon, Hyuk-Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10229625/
https://www.ncbi.nlm.nih.gov/pubmed/37253737
http://dx.doi.org/10.1038/s41467-023-38918-3
_version_ 1785051304575369216
author Lim, Hyeongtae
Kwon, Hyeokjin
Kang, Hongki
Jang, Jae Eun
Kwon, Hyuk-Jun
author_facet Lim, Hyeongtae
Kwon, Hyeokjin
Kang, Hongki
Jang, Jae Eun
Kwon, Hyuk-Jun
author_sort Lim, Hyeongtae
collection PubMed
description Due to rapid urbanization worldwide, monitoring the concentration of nitrogen dioxide (NO(2)), which causes cardiovascular and respiratory diseases, has attracted considerable attention. Developing real-time sensors to detect parts-per-billion (ppb)-level NO(2) remains challenging due to limited sensitivity, response, and recovery characteristics. Herein, we report a hybrid structure of Cu(3)HHTP(2), 2D semiconducting metal-organic frameworks (MOFs), and laser-induced graphene (LIG) for high-performance NO(2) sensing. The unique hierarchical pore architecture of LIG@Cu(3)HHTP(2) promotes mass transport of gas molecules and takes full advantage of the large surface area and porosity of MOFs, enabling highly rapid and sensitive responses to NO(2). Consequently, LIG@Cu(3)HHTP(2) shows one of the fastest responses and lowest limit of detection at room temperature compared with state-of-the-art NO(2) sensors. Additionally, by employing LIG as a growth platform, flexibility and patterning strategies are achieved, which are the main challenges for MOF-based electronic devices. These results provide key insight into applying MOFtronics as high-performance healthcare devices.
format Online
Article
Text
id pubmed-10229625
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher Nature Publishing Group UK
record_format MEDLINE/PubMed
spelling pubmed-102296252023-06-01 Semiconducting MOFs on ultraviolet laser-induced graphene with a hierarchical pore architecture for NO(2) monitoring Lim, Hyeongtae Kwon, Hyeokjin Kang, Hongki Jang, Jae Eun Kwon, Hyuk-Jun Nat Commun Article Due to rapid urbanization worldwide, monitoring the concentration of nitrogen dioxide (NO(2)), which causes cardiovascular and respiratory diseases, has attracted considerable attention. Developing real-time sensors to detect parts-per-billion (ppb)-level NO(2) remains challenging due to limited sensitivity, response, and recovery characteristics. Herein, we report a hybrid structure of Cu(3)HHTP(2), 2D semiconducting metal-organic frameworks (MOFs), and laser-induced graphene (LIG) for high-performance NO(2) sensing. The unique hierarchical pore architecture of LIG@Cu(3)HHTP(2) promotes mass transport of gas molecules and takes full advantage of the large surface area and porosity of MOFs, enabling highly rapid and sensitive responses to NO(2). Consequently, LIG@Cu(3)HHTP(2) shows one of the fastest responses and lowest limit of detection at room temperature compared with state-of-the-art NO(2) sensors. Additionally, by employing LIG as a growth platform, flexibility and patterning strategies are achieved, which are the main challenges for MOF-based electronic devices. These results provide key insight into applying MOFtronics as high-performance healthcare devices. Nature Publishing Group UK 2023-05-30 /pmc/articles/PMC10229625/ /pubmed/37253737 http://dx.doi.org/10.1038/s41467-023-38918-3 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Lim, Hyeongtae
Kwon, Hyeokjin
Kang, Hongki
Jang, Jae Eun
Kwon, Hyuk-Jun
Semiconducting MOFs on ultraviolet laser-induced graphene with a hierarchical pore architecture for NO(2) monitoring
title Semiconducting MOFs on ultraviolet laser-induced graphene with a hierarchical pore architecture for NO(2) monitoring
title_full Semiconducting MOFs on ultraviolet laser-induced graphene with a hierarchical pore architecture for NO(2) monitoring
title_fullStr Semiconducting MOFs on ultraviolet laser-induced graphene with a hierarchical pore architecture for NO(2) monitoring
title_full_unstemmed Semiconducting MOFs on ultraviolet laser-induced graphene with a hierarchical pore architecture for NO(2) monitoring
title_short Semiconducting MOFs on ultraviolet laser-induced graphene with a hierarchical pore architecture for NO(2) monitoring
title_sort semiconducting mofs on ultraviolet laser-induced graphene with a hierarchical pore architecture for no(2) monitoring
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10229625/
https://www.ncbi.nlm.nih.gov/pubmed/37253737
http://dx.doi.org/10.1038/s41467-023-38918-3
work_keys_str_mv AT limhyeongtae semiconductingmofsonultravioletlaserinducedgraphenewithahierarchicalporearchitectureforno2monitoring
AT kwonhyeokjin semiconductingmofsonultravioletlaserinducedgraphenewithahierarchicalporearchitectureforno2monitoring
AT kanghongki semiconductingmofsonultravioletlaserinducedgraphenewithahierarchicalporearchitectureforno2monitoring
AT jangjaeeun semiconductingmofsonultravioletlaserinducedgraphenewithahierarchicalporearchitectureforno2monitoring
AT kwonhyukjun semiconductingmofsonultravioletlaserinducedgraphenewithahierarchicalporearchitectureforno2monitoring