Cargando…

Aromaticity: Quo Vadis

Aromaticity is one of the most deeply rooted concepts in chemistry. But why, if two-thirds of existing compounds can be classified as aromatic, is there no consensus on what aromaticity is? σ−, π−, δ−, spherical, Möbius, or all-metal aromaticity… why are so many attributes needed to specify a proper...

Descripción completa

Detalles Bibliográficos
Autores principales: Merino, Gabriel, Solà, Miquel, Fernández, Israel, Foroutan-Nejad, Cina, Lazzeretti, Paolo, Frenking, Gernot, Anderson, Harry L., Sundholm, Dage, Cossío, Fernando P., Petrukhina, Marina A., Wu, Jishan, Wu, Judy I., Restrepo, Albeiro
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10231312/
https://www.ncbi.nlm.nih.gov/pubmed/37265727
http://dx.doi.org/10.1039/d2sc04998h
_version_ 1785051716447633408
author Merino, Gabriel
Solà, Miquel
Fernández, Israel
Foroutan-Nejad, Cina
Lazzeretti, Paolo
Frenking, Gernot
Anderson, Harry L.
Sundholm, Dage
Cossío, Fernando P.
Petrukhina, Marina A.
Wu, Jishan
Wu, Judy I.
Restrepo, Albeiro
author_facet Merino, Gabriel
Solà, Miquel
Fernández, Israel
Foroutan-Nejad, Cina
Lazzeretti, Paolo
Frenking, Gernot
Anderson, Harry L.
Sundholm, Dage
Cossío, Fernando P.
Petrukhina, Marina A.
Wu, Jishan
Wu, Judy I.
Restrepo, Albeiro
author_sort Merino, Gabriel
collection PubMed
description Aromaticity is one of the most deeply rooted concepts in chemistry. But why, if two-thirds of existing compounds can be classified as aromatic, is there no consensus on what aromaticity is? σ−, π−, δ−, spherical, Möbius, or all-metal aromaticity… why are so many attributes needed to specify a property? Is aromaticity a dubious concept? This perspective aims to reflect where the aromaticity community is and where it is going.
format Online
Article
Text
id pubmed-10231312
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-102313122023-06-01 Aromaticity: Quo Vadis Merino, Gabriel Solà, Miquel Fernández, Israel Foroutan-Nejad, Cina Lazzeretti, Paolo Frenking, Gernot Anderson, Harry L. Sundholm, Dage Cossío, Fernando P. Petrukhina, Marina A. Wu, Jishan Wu, Judy I. Restrepo, Albeiro Chem Sci Chemistry Aromaticity is one of the most deeply rooted concepts in chemistry. But why, if two-thirds of existing compounds can be classified as aromatic, is there no consensus on what aromaticity is? σ−, π−, δ−, spherical, Möbius, or all-metal aromaticity… why are so many attributes needed to specify a property? Is aromaticity a dubious concept? This perspective aims to reflect where the aromaticity community is and where it is going. The Royal Society of Chemistry 2023-02-22 /pmc/articles/PMC10231312/ /pubmed/37265727 http://dx.doi.org/10.1039/d2sc04998h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Merino, Gabriel
Solà, Miquel
Fernández, Israel
Foroutan-Nejad, Cina
Lazzeretti, Paolo
Frenking, Gernot
Anderson, Harry L.
Sundholm, Dage
Cossío, Fernando P.
Petrukhina, Marina A.
Wu, Jishan
Wu, Judy I.
Restrepo, Albeiro
Aromaticity: Quo Vadis
title Aromaticity: Quo Vadis
title_full Aromaticity: Quo Vadis
title_fullStr Aromaticity: Quo Vadis
title_full_unstemmed Aromaticity: Quo Vadis
title_short Aromaticity: Quo Vadis
title_sort aromaticity: quo vadis
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10231312/
https://www.ncbi.nlm.nih.gov/pubmed/37265727
http://dx.doi.org/10.1039/d2sc04998h
work_keys_str_mv AT merinogabriel aromaticityquovadis
AT solamiquel aromaticityquovadis
AT fernandezisrael aromaticityquovadis
AT foroutannejadcina aromaticityquovadis
AT lazzerettipaolo aromaticityquovadis
AT frenkinggernot aromaticityquovadis
AT andersonharryl aromaticityquovadis
AT sundholmdage aromaticityquovadis
AT cossiofernandop aromaticityquovadis
AT petrukhinamarinaa aromaticityquovadis
AT wujishan aromaticityquovadis
AT wujudyi aromaticityquovadis
AT restrepoalbeiro aromaticityquovadis