Cargando…
Sonophotocatalytic Degradation of Fast Yellow AB and Remazol Brilliant Violet-5R by Using Ag-Impregnated ZnO as a Photocatalyst
[Image: see text] The fundamental aim of this project was to assess the sonophotocatalytic degradation of textile dyes mostly eluted from industries into wastewater. Such a pretreatment of wastewater makes the water suitable for drinking and irrigation purposes and thereby helps protect the ecosyste...
Autores principales: | , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10233690/ https://www.ncbi.nlm.nih.gov/pubmed/37273626 http://dx.doi.org/10.1021/acsomega.3c00171 |
_version_ | 1785052312090181632 |
---|---|
author | Aziz, Nosheen Rasool, Shagufta Ullah, Toheed Khitab, Fatima Halim, Sobia Ahsan Bawazeer, Sami Khan, Ajmal Al-Harrasi, Ahmed |
author_facet | Aziz, Nosheen Rasool, Shagufta Ullah, Toheed Khitab, Fatima Halim, Sobia Ahsan Bawazeer, Sami Khan, Ajmal Al-Harrasi, Ahmed |
author_sort | Aziz, Nosheen |
collection | PubMed |
description | [Image: see text] The fundamental aim of this project was to assess the sonophotocatalytic degradation of textile dyes mostly eluted from industries into wastewater. Such a pretreatment of wastewater makes the water suitable for drinking and irrigation purposes and thereby helps protect the ecosystem. The main objective of this research was to degrade real samples and laboratory-prepared samples sonophotocatalytically using a silver-impregnated ZnO photocatalyst. Reactive dyes, including Fast Yellow AB (FY AB) and Remazol Brilliant Violet-5R (RBV-5R), were degraded via this technique under optimum and enhanced conditions. The photocatalyst was synthesized through a wet impregnation process and characterized by scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) analysis, Fourier transform infrared (FTIR) spectroscopy, and UV/vis spectroscopy to examine the morphology, composition, and functional groups of the photocatalyst. Parameters including pH, dosage, dye concentration, scavengers, and effects of oxidizing agents were considered. Under optimal conditions, the degradations were 95.7 and 88.9% for RBV-5R and FY AB, respectively, in 60 min. The pH and oxidizing agents played important roles in the degradation process. Only 43.8 and 32.5% of RBV-5R and FY AB, respectively, were degraded in the absence of an oxidizing agent. With the addition of oxidizing agents, 95.7 and 88.9% of RBV-5R and FY AB degradation occurred, respectively. The optimal pH values for RBV 5-R and FY-AB were 8 and 12, respectively. A comparison between the photocatalytic and sonophotocatalytic processes revealed degradation efficiencies of 41 and 33% for RBV-5R and FY-AB, respectively, by the photocatalytic process. Therefore, results indicate the productivity of the sonophotocatalytic degradation process. |
format | Online Article Text |
id | pubmed-10233690 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-102336902023-06-02 Sonophotocatalytic Degradation of Fast Yellow AB and Remazol Brilliant Violet-5R by Using Ag-Impregnated ZnO as a Photocatalyst Aziz, Nosheen Rasool, Shagufta Ullah, Toheed Khitab, Fatima Halim, Sobia Ahsan Bawazeer, Sami Khan, Ajmal Al-Harrasi, Ahmed ACS Omega [Image: see text] The fundamental aim of this project was to assess the sonophotocatalytic degradation of textile dyes mostly eluted from industries into wastewater. Such a pretreatment of wastewater makes the water suitable for drinking and irrigation purposes and thereby helps protect the ecosystem. The main objective of this research was to degrade real samples and laboratory-prepared samples sonophotocatalytically using a silver-impregnated ZnO photocatalyst. Reactive dyes, including Fast Yellow AB (FY AB) and Remazol Brilliant Violet-5R (RBV-5R), were degraded via this technique under optimum and enhanced conditions. The photocatalyst was synthesized through a wet impregnation process and characterized by scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) analysis, Fourier transform infrared (FTIR) spectroscopy, and UV/vis spectroscopy to examine the morphology, composition, and functional groups of the photocatalyst. Parameters including pH, dosage, dye concentration, scavengers, and effects of oxidizing agents were considered. Under optimal conditions, the degradations were 95.7 and 88.9% for RBV-5R and FY AB, respectively, in 60 min. The pH and oxidizing agents played important roles in the degradation process. Only 43.8 and 32.5% of RBV-5R and FY AB, respectively, were degraded in the absence of an oxidizing agent. With the addition of oxidizing agents, 95.7 and 88.9% of RBV-5R and FY AB degradation occurred, respectively. The optimal pH values for RBV 5-R and FY-AB were 8 and 12, respectively. A comparison between the photocatalytic and sonophotocatalytic processes revealed degradation efficiencies of 41 and 33% for RBV-5R and FY-AB, respectively, by the photocatalytic process. Therefore, results indicate the productivity of the sonophotocatalytic degradation process. American Chemical Society 2023-05-15 /pmc/articles/PMC10233690/ /pubmed/37273626 http://dx.doi.org/10.1021/acsomega.3c00171 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Aziz, Nosheen Rasool, Shagufta Ullah, Toheed Khitab, Fatima Halim, Sobia Ahsan Bawazeer, Sami Khan, Ajmal Al-Harrasi, Ahmed Sonophotocatalytic Degradation of Fast Yellow AB and Remazol Brilliant Violet-5R by Using Ag-Impregnated ZnO as a Photocatalyst |
title | Sonophotocatalytic Degradation of Fast Yellow AB and
Remazol Brilliant Violet-5R by Using Ag-Impregnated ZnO as a Photocatalyst |
title_full | Sonophotocatalytic Degradation of Fast Yellow AB and
Remazol Brilliant Violet-5R by Using Ag-Impregnated ZnO as a Photocatalyst |
title_fullStr | Sonophotocatalytic Degradation of Fast Yellow AB and
Remazol Brilliant Violet-5R by Using Ag-Impregnated ZnO as a Photocatalyst |
title_full_unstemmed | Sonophotocatalytic Degradation of Fast Yellow AB and
Remazol Brilliant Violet-5R by Using Ag-Impregnated ZnO as a Photocatalyst |
title_short | Sonophotocatalytic Degradation of Fast Yellow AB and
Remazol Brilliant Violet-5R by Using Ag-Impregnated ZnO as a Photocatalyst |
title_sort | sonophotocatalytic degradation of fast yellow ab and
remazol brilliant violet-5r by using ag-impregnated zno as a photocatalyst |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10233690/ https://www.ncbi.nlm.nih.gov/pubmed/37273626 http://dx.doi.org/10.1021/acsomega.3c00171 |
work_keys_str_mv | AT aziznosheen sonophotocatalyticdegradationoffastyellowabandremazolbrilliantviolet5rbyusingagimpregnatedznoasaphotocatalyst AT rasoolshagufta sonophotocatalyticdegradationoffastyellowabandremazolbrilliantviolet5rbyusingagimpregnatedznoasaphotocatalyst AT ullahtoheed sonophotocatalyticdegradationoffastyellowabandremazolbrilliantviolet5rbyusingagimpregnatedznoasaphotocatalyst AT khitabfatima sonophotocatalyticdegradationoffastyellowabandremazolbrilliantviolet5rbyusingagimpregnatedznoasaphotocatalyst AT halimsobiaahsan sonophotocatalyticdegradationoffastyellowabandremazolbrilliantviolet5rbyusingagimpregnatedznoasaphotocatalyst AT bawazeersami sonophotocatalyticdegradationoffastyellowabandremazolbrilliantviolet5rbyusingagimpregnatedznoasaphotocatalyst AT khanajmal sonophotocatalyticdegradationoffastyellowabandremazolbrilliantviolet5rbyusingagimpregnatedznoasaphotocatalyst AT alharrasiahmed sonophotocatalyticdegradationoffastyellowabandremazolbrilliantviolet5rbyusingagimpregnatedznoasaphotocatalyst |