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Ultrafast Water H-Bond Rearrangement in a Metal–Organic Framework Probed by Femtosecond Time-Resolved Infrared Spectroscopy

[Image: see text] We investigated the water H-bond network and its dynamics in Ni(2)Cl(2)BTDD, a prototypical MOF for atmospheric water harvesting, using linear and ultrafast IR spectroscopy. Utilizing isotopic labeling and infrared spectroscopy, we found that water forms an extensive H-bonding netw...

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Detalles Bibliográficos
Autores principales: Valentine, Mason L., Yin, Guoxin, Oppenheim, Julius J., Dincǎ, Mircea, Xiong, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10236489/
https://www.ncbi.nlm.nih.gov/pubmed/37201196
http://dx.doi.org/10.1021/jacs.3c01728