Single molecule aggregation-induced dual and white-light emissive etherified aroyl-S,N-ketene acetals via one-pot synthesis

Etherified aroyl-S,N-ketene acetals are readily synthesized by a novel one-pot addition–elimination-Williamson-etherification sequence. Although the underlying chromophore remains constant, derivatives show pronounced color-tuning of solid-state emission and AIE characteristics, whereas a hydroxy-me...

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Detalles Bibliográficos
Autores principales: Biesen, Lukas, Müller, Thomas J. J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10240259/
https://www.ncbi.nlm.nih.gov/pubmed/37283871
http://dx.doi.org/10.1039/d3ra02935b
Descripción
Sumario:Etherified aroyl-S,N-ketene acetals are readily synthesized by a novel one-pot addition–elimination-Williamson-etherification sequence. Although the underlying chromophore remains constant, derivatives show pronounced color-tuning of solid-state emission and AIE characteristics, whereas a hydroxy-methyl derivative represents an easily accessible mono molecular aggregation-induced white-light emitter.

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