Controlling the magnetic structure in W-type hexaferrites

W-type hexaferrites with varied Co/Zn ratios were synthesized and the magnetic order was investigated using neutron powder diffraction. In SrCo(2)Fe(16)O(27) and SrCoZnFe(16)O(27) a planar (Cm′cm′) magnetic ordering was found, rather than the uniaxial ordering (P6(3)/mm′c′) found in SrZn(2)Fe(16)O(27) which is common in most W-type hexaferrites. In all three studied samples, non-collinear terms were present in the magnetic ordering. One of the non-collinear terms is common to the planar ordering in SrCoZnFe(16)O(27) and uniaxial ordering in SrZn(2)Fe(16)O(27), which could be a sign of an imminent transition in the magnetic structure. The thermomagnetic measurements revealed magnetic transitions at 520 and 360 K for SrCo(2)Fe(16)O(27) and SrCoZnFe(16)O(27), and Curie temperatures of 780 and 680 K, respectively, while SrZn(2)Fe(16)O(27) showed no transition but a Curie temperature at 590 K. This leads to the conclusion that the magnetic transition can be adjusted by fine-tuning the Co/Zn stoichiometry in the sample.