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An efficient protocol for the synthesis of pyridines and hydroquinolones using IRMOF-3/GO/CuFe(2)O(4) composite as a magnetically separable heterogeneous catalyst

This study reports a facile and cost-effective technique for preparing magnetic copper ferrite nanoparticles supported on IRMOF-3/GO [IRMOF-3/GO/CuFe(2)O(4)]. The synthesized IRMOF-3/GO/CuFe(2)O(4) was characterized with IR, SEM, TGA, XRD, BET, EDX, VSM, and elemental mapping. The prepared catalyst...

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Detalles Bibliográficos
Autores principales: Ghasemzadeh, Mohammad Ali, Mirhosseini-Eshkevari, Boshra, Dadashi, Jaber
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10241797/
https://www.ncbi.nlm.nih.gov/pubmed/37277460
http://dx.doi.org/10.1038/s41598-023-36115-2
Descripción
Sumario:This study reports a facile and cost-effective technique for preparing magnetic copper ferrite nanoparticles supported on IRMOF-3/GO [IRMOF-3/GO/CuFe(2)O(4)]. The synthesized IRMOF-3/GO/CuFe(2)O(4) was characterized with IR, SEM, TGA, XRD, BET, EDX, VSM, and elemental mapping. The prepared catalyst revealed higher catalytic behavior in synthesizing heterocyclic compounds through a one-pot reaction between various aromatic aldehydes, diverse primary amines, malononitrile, and dimedone under ultrasound irradiations. Among the notable features of this technique are higher efficiency, easy recovery from the reaction mixture, removal of a heterogeneous catalyst, and uncomplicated route. In this catalytic system, the activity level was almost constant after various stages of reuse and recovery.