Comparison of group 4 and thorium M(iv) substituted cyclopentadienyl silanide complexes

We report the synthesis and characterisation of a series of M(iv) substituted cyclopentadienyl hypersilanide complexes of the general formula [M(Cp(R))(2){Si(SiMe(3))(3)}(X)] (M = Hf, Th; Cp(R) = Cp′, {C(5)H(4)(SiMe(3))} or Cp′′, {C(5)H(3)(SiMe(3))(2)-1,3}; X = Cl, C(3)H(5)). The separate salt metat...

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Detalles Bibliográficos
Autores principales: Réant, Benjamin L. L., De Alwis Jayasinghe, Dukula, Wooles, Ashley J., Liddle, Stephen T., Mills, David P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242453/
https://www.ncbi.nlm.nih.gov/pubmed/37199085
http://dx.doi.org/10.1039/d3dt00987d

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242453/
https://www.ncbi.nlm.nih.gov/pubmed/37199085
http://dx.doi.org/10.1039/d3dt00987d

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