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Comparison of group 4 and thorium M(iv) substituted cyclopentadienyl silanide complexes
We report the synthesis and characterisation of a series of M(iv) substituted cyclopentadienyl hypersilanide complexes of the general formula [M(Cp(R))(2){Si(SiMe(3))(3)}(X)] (M = Hf, Th; Cp(R) = Cp′, {C(5)H(4)(SiMe(3))} or Cp′′, {C(5)H(3)(SiMe(3))(2)-1,3}; X = Cl, C(3)H(5)). The separate salt metat...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242453/ https://www.ncbi.nlm.nih.gov/pubmed/37199085 http://dx.doi.org/10.1039/d3dt00987d |