5-[(4-Methyl­phen­yl)sulfon­yl]-1-phenyl­thio­pyrano[4,3-b]indole-3(5H)-thione di­chloro­methane monosolvate

Rhodium-catalyzed [2+2+2] cyclo­addition of carbon di­sulfide to o,N-dialkynyl­tosyl­anilines gives two isomeric indolo­thio­pyran­thio­nes, a violet and a red isomer. This is the first crystal structure of a red isomer, which crystallizes with one solvent mol­ecule of di­chloro­methane in the asymm...

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Detalles Bibliográficos
Autores principales: Dassonneville, Benjamin, Schollmeyer, Dieter, Detert, Heiner
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242727/
https://www.ncbi.nlm.nih.gov/pubmed/37287857
http://dx.doi.org/10.1107/S2414314623003541
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author Dassonneville, Benjamin
Schollmeyer, Dieter
Detert, Heiner
author_facet Dassonneville, Benjamin
Schollmeyer, Dieter
Detert, Heiner
author_sort Dassonneville, Benjamin
collection PubMed
description Rhodium-catalyzed [2+2+2] cyclo­addition of carbon di­sulfide to o,N-dialkynyl­tosyl­anilines gives two isomeric indolo­thio­pyran­thio­nes, a violet and a red isomer. This is the first crystal structure of a red isomer, which crystallizes with one solvent mol­ecule of di­chloro­methane in the asymmetric unit, C(24)H(17)NO(2)S(3)·CH(2)Cl(2). In the extended structure, centrosymmetric pairs of the planar annulated system are arranged in strands and solvent mol­ecules fill the space between the strands. [Image: see text]
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spelling pubmed-102427272023-06-07 5-[(4-Methyl­phen­yl)sulfon­yl]-1-phenyl­thio­pyrano[4,3-b]indole-3(5H)-thione di­chloro­methane monosolvate Dassonneville, Benjamin Schollmeyer, Dieter Detert, Heiner IUCrdata Data Reports Rhodium-catalyzed [2+2+2] cyclo­addition of carbon di­sulfide to o,N-dialkynyl­tosyl­anilines gives two isomeric indolo­thio­pyran­thio­nes, a violet and a red isomer. This is the first crystal structure of a red isomer, which crystallizes with one solvent mol­ecule of di­chloro­methane in the asymmetric unit, C(24)H(17)NO(2)S(3)·CH(2)Cl(2). In the extended structure, centrosymmetric pairs of the planar annulated system are arranged in strands and solvent mol­ecules fill the space between the strands. [Image: see text] International Union of Crystallography 2023-05-12 /pmc/articles/PMC10242727/ /pubmed/37287857 http://dx.doi.org/10.1107/S2414314623003541 Text en © Dassonneville et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Dassonneville, Benjamin
Schollmeyer, Dieter
Detert, Heiner
5-[(4-Methyl­phen­yl)sulfon­yl]-1-phenyl­thio­pyrano[4,3-b]indole-3(5H)-thione di­chloro­methane monosolvate
title 5-[(4-Methyl­phen­yl)sulfon­yl]-1-phenyl­thio­pyrano[4,3-b]indole-3(5H)-thione di­chloro­methane monosolvate
title_full 5-[(4-Methyl­phen­yl)sulfon­yl]-1-phenyl­thio­pyrano[4,3-b]indole-3(5H)-thione di­chloro­methane monosolvate
title_fullStr 5-[(4-Methyl­phen­yl)sulfon­yl]-1-phenyl­thio­pyrano[4,3-b]indole-3(5H)-thione di­chloro­methane monosolvate
title_full_unstemmed 5-[(4-Methyl­phen­yl)sulfon­yl]-1-phenyl­thio­pyrano[4,3-b]indole-3(5H)-thione di­chloro­methane monosolvate
title_short 5-[(4-Methyl­phen­yl)sulfon­yl]-1-phenyl­thio­pyrano[4,3-b]indole-3(5H)-thione di­chloro­methane monosolvate
title_sort 5-[(4-methyl­phen­yl)sulfon­yl]-1-phenyl­thio­pyrano[4,3-b]indole-3(5h)-thione di­chloro­methane monosolvate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242727/
https://www.ncbi.nlm.nih.gov/pubmed/37287857
http://dx.doi.org/10.1107/S2414314623003541
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AT detertheiner 54methylphenylsulfonyl1phenylthiopyrano43bindole35hthionedichloromethanemonosolvate

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