Cargando…
(2,2′-Bipyridyl)(η(6)-p-cymene)iodidoruthenium(II) hexafluoridophosphate
The title compound, having the molecular formula [RuI(η(6)-C(10)H(14))(C(10)H(8)N(2))]PF(6), crystallizes in the triclinic P [Image: see text] (Z = 2) space group as a half-sandwich complex resembling a three-legged piano stool. Important geometrical parameters include Ru—cymene centroid = 1.6902 (...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2023
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242728/ https://www.ncbi.nlm.nih.gov/pubmed/37287858 http://dx.doi.org/10.1107/S2414314623003929 |
| Sumario: | The title compound, having the molecular formula [RuI(η(6)-C(10)H(14))(C(10)H(8)N(2))]PF(6), crystallizes in the triclinic P [Image: see text] (Z = 2) space group as a half-sandwich complex resembling a three-legged piano stool. Important geometrical parameters include Ru—cymene centroid = 1.6902 (17) Å, Ru—I = 2.6958 (5) Å, [Ru—N](avg) = 2.072 (3) Å, N1—Ru—N2 = 76.86 (12)° and a dihedral angle between the planes of the two rings of the bipyridyl system of 5.9 (2)°. The PF(6) (−) ion was treated with a twofold disorder model, refining to a 65.0 (8):35.0 (8) occupancy ratio. The crystal packing features C—H⋯F/I interactions. [Image: see text] |
|---|