(2,2′-Bipyrid­yl)(η(6)-p-cymene)iodidoruthenium(II) hexa­fluorido­phosphate

The title compound, having the mol­ecular formula [RuI(η(6)-C(10)H(14))(C(10)H(8)N(2))]PF(6), crystallizes in the triclinic P [Image: see text] (Z = 2) space group as a half-sandwich complex resembling a three-legged piano stool. Important geometrical parameters include Ru—cymene centroid = 1.6902 (...

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Detalles Bibliográficos
Autores principales: Kelani, Monsuru T., Muller, Alfred, Lammertsma, Koop
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Data Reports
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242728/
https://www.ncbi.nlm.nih.gov/pubmed/37287858
http://dx.doi.org/10.1107/S2414314623003929
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author Kelani, Monsuru T.
Muller, Alfred
Lammertsma, Koop
author_facet Kelani, Monsuru T.
Muller, Alfred
Lammertsma, Koop
author_sort Kelani, Monsuru T.
collection PubMed
description The title compound, having the mol­ecular formula [RuI(η(6)-C(10)H(14))(C(10)H(8)N(2))]PF(6), crystallizes in the triclinic P [Image: see text] (Z = 2) space group as a half-sandwich complex resembling a three-legged piano stool. Important geometrical parameters include Ru—cymene centroid = 1.6902 (17) Å, Ru—I = 2.6958 (5) Å, [Ru—N](avg) = 2.072 (3) Å, N1—Ru—N2 = 76.86 (12)° and a dihedral angle between the planes of the two rings of the bipyridyl system of 5.9 (2)°. The PF(6) (−) ion was treated with a twofold disorder model, refining to a 65.0 (8):35.0 (8) occupancy ratio. The crystal packing features C—H⋯F/I inter­actions. [Image: see text]
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spelling pubmed-102427282023-06-07 (2,2′-Bipyrid­yl)(η(6)-p-cymene)iodidoruthenium(II) hexa­fluorido­phosphate Kelani, Monsuru T. Muller, Alfred Lammertsma, Koop IUCrdata Data Reports The title compound, having the mol­ecular formula [RuI(η(6)-C(10)H(14))(C(10)H(8)N(2))]PF(6), crystallizes in the triclinic P [Image: see text] (Z = 2) space group as a half-sandwich complex resembling a three-legged piano stool. Important geometrical parameters include Ru—cymene centroid = 1.6902 (17) Å, Ru—I = 2.6958 (5) Å, [Ru—N](avg) = 2.072 (3) Å, N1—Ru—N2 = 76.86 (12)° and a dihedral angle between the planes of the two rings of the bipyridyl system of 5.9 (2)°. The PF(6) (−) ion was treated with a twofold disorder model, refining to a 65.0 (8):35.0 (8) occupancy ratio. The crystal packing features C—H⋯F/I inter­actions. [Image: see text] International Union of Crystallography 2023-05-12 /pmc/articles/PMC10242728/ /pubmed/37287858 http://dx.doi.org/10.1107/S2414314623003929 Text en © Kelani et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Data Reports
Kelani, Monsuru T.
Muller, Alfred
Lammertsma, Koop
(2,2′-Bipyrid­yl)(η(6)-p-cymene)iodidoruthenium(II) hexa­fluorido­phosphate
title (2,2′-Bipyrid­yl)(η(6)-p-cymene)iodidoruthenium(II) hexa­fluorido­phosphate
title_full (2,2′-Bipyrid­yl)(η(6)-p-cymene)iodidoruthenium(II) hexa­fluorido­phosphate
title_fullStr (2,2′-Bipyrid­yl)(η(6)-p-cymene)iodidoruthenium(II) hexa­fluorido­phosphate
title_full_unstemmed (2,2′-Bipyrid­yl)(η(6)-p-cymene)iodidoruthenium(II) hexa­fluorido­phosphate
title_short (2,2′-Bipyrid­yl)(η(6)-p-cymene)iodidoruthenium(II) hexa­fluorido­phosphate
title_sort (2,2′-bipyrid­yl)(η(6)-p-cymene)iodidoruthenium(ii) hexa­fluorido­phosphate
topic Data Reports
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242728/
https://www.ncbi.nlm.nih.gov/pubmed/37287858
http://dx.doi.org/10.1107/S2414314623003929
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AT lammertsmakoop 22bipyridylē6pcymeneiodidorutheniumiihexafluoridophosphate

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