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Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate
The title compound {systematic name: bis[2-(1,3-dioxoisoindol-2-yl)ethyl]azanium chloride dihydrate}, C(20)H(18)N(3)O(4) (+)·Cl(−)·2H(2)O, is a phthalimide-protected polyamine that was synthesized by a previous method. It was characterized by ESI–MS, (1)H NMR, and FT–IR. Crystals were grown from...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242743/ https://www.ncbi.nlm.nih.gov/pubmed/37288457 http://dx.doi.org/10.1107/S2056989023004565 |
| _version_ | 1785054283272552448 |
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| author | Young, Barry S. Lee, Jamie L. Gembicky, Milan Bailey, Jake Smith, Gary L. N. |
| author_facet | Young, Barry S. Lee, Jamie L. Gembicky, Milan Bailey, Jake Smith, Gary L. N. |
| author_sort | Young, Barry S. |
| collection | PubMed |
| description | The title compound {systematic name: bis[2-(1,3-dioxoisoindol-2-yl)ethyl]azanium chloride dihydrate}, C(20)H(18)N(3)O(4) (+)·Cl(−)·2H(2)O, is a phthalimide-protected polyamine that was synthesized by a previous method. It was characterized by ESI–MS, (1)H NMR, and FT–IR. Crystals were grown from a solution of H(2)O and 0.1 M HCl. The central nitrogen atom is protonated and forms hydrogen bonds with the chloride ion and a water molecule. The two phthalimide units make a dihedral angle of 22.07 (3)°. The crystal packing features a hydrogen-bond network, two-coordinated chloride, and off-set π–π stacking. |
| format | Online Article Text |
| id | pubmed-10242743 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2023 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-102427432023-06-07 Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate Young, Barry S. Lee, Jamie L. Gembicky, Milan Bailey, Jake Smith, Gary L. N. Acta Crystallogr E Crystallogr Commun Research Communications The title compound {systematic name: bis[2-(1,3-dioxoisoindol-2-yl)ethyl]azanium chloride dihydrate}, C(20)H(18)N(3)O(4) (+)·Cl(−)·2H(2)O, is a phthalimide-protected polyamine that was synthesized by a previous method. It was characterized by ESI–MS, (1)H NMR, and FT–IR. Crystals were grown from a solution of H(2)O and 0.1 M HCl. The central nitrogen atom is protonated and forms hydrogen bonds with the chloride ion and a water molecule. The two phthalimide units make a dihedral angle of 22.07 (3)°. The crystal packing features a hydrogen-bond network, two-coordinated chloride, and off-set π–π stacking. International Union of Crystallography 2023-05-26 /pmc/articles/PMC10242743/ /pubmed/37288457 http://dx.doi.org/10.1107/S2056989023004565 Text en © Young et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Research Communications Young, Barry S. Lee, Jamie L. Gembicky, Milan Bailey, Jake Smith, Gary L. N. Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_full | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_fullStr | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_full_unstemmed | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_short | Synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| title_sort | synthesis and crystal structure of bis(2-phthalimidoethyl)ammonium chloride dihydrate |
| topic | Research Communications |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242743/ https://www.ncbi.nlm.nih.gov/pubmed/37288457 http://dx.doi.org/10.1107/S2056989023004565 |
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