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Triarylamminium Radical Cation Facilitates the Deprotection of tert-Butyl Groups in Esters, Ethers, Carbonates, and Carbamates
[Image: see text] We report a catalytic protocol for mild OtBu deprotection using two commercial reagents: the tris-4-bromophenylamminium radical cation, commonly known as magic blue (MB(•+)), and triethylsilane. Magic blue catalytically facilitates the cleavage of the C–O bond in tert-butyl carbama...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10242758/ https://www.ncbi.nlm.nih.gov/pubmed/37126731 http://dx.doi.org/10.1021/acs.joc.3c00238 |