Synthesis of Cationic Azatriphenylene Derivatives by Electrochemical Intramolecular Pyridination and Characterization of Their Optoelectronic Properties

[Image: see text] Here, a facile and selective synthesis method for cationic azatriphenylene derivatives was established by electrochemical intramolecular cyclization, where atom-economical C–H pyridination without a transition-metal catalyst or an oxidant is a key step. The proposed protocol is a p...

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Autores principales: Ohno, Yushi, Ando, Shogo, Furusho, Daisuke, Hifumi, Ryoyu, Nagata, Yuuya, Tomita, Ikuyoshi, Inagi, Shinsuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10243103/
https://www.ncbi.nlm.nih.gov/pubmed/37222538
http://dx.doi.org/10.1021/acs.orglett.3c01341
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author Ohno, Yushi
Ando, Shogo
Furusho, Daisuke
Hifumi, Ryoyu
Nagata, Yuuya
Tomita, Ikuyoshi
Inagi, Shinsuke
author_facet Ohno, Yushi
Ando, Shogo
Furusho, Daisuke
Hifumi, Ryoyu
Nagata, Yuuya
Tomita, Ikuyoshi
Inagi, Shinsuke
author_sort Ohno, Yushi
collection PubMed
description [Image: see text] Here, a facile and selective synthesis method for cationic azatriphenylene derivatives was established by electrochemical intramolecular cyclization, where atom-economical C–H pyridination without a transition-metal catalyst or an oxidant is a key step. The proposed protocol is a practical strategy for the late-stage introduction of cationic nitrogen (N(+)) into π-electron systems and broadens the scope of molecular design of N(+)-doped polycyclic aromatic hydrocarbons.
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spelling pubmed-102431032023-06-07 Synthesis of Cationic Azatriphenylene Derivatives by Electrochemical Intramolecular Pyridination and Characterization of Their Optoelectronic Properties Ohno, Yushi Ando, Shogo Furusho, Daisuke Hifumi, Ryoyu Nagata, Yuuya Tomita, Ikuyoshi Inagi, Shinsuke Org Lett [Image: see text] Here, a facile and selective synthesis method for cationic azatriphenylene derivatives was established by electrochemical intramolecular cyclization, where atom-economical C–H pyridination without a transition-metal catalyst or an oxidant is a key step. The proposed protocol is a practical strategy for the late-stage introduction of cationic nitrogen (N(+)) into π-electron systems and broadens the scope of molecular design of N(+)-doped polycyclic aromatic hydrocarbons. American Chemical Society 2023-05-24 /pmc/articles/PMC10243103/ /pubmed/37222538 http://dx.doi.org/10.1021/acs.orglett.3c01341 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Ohno, Yushi
Ando, Shogo
Furusho, Daisuke
Hifumi, Ryoyu
Nagata, Yuuya
Tomita, Ikuyoshi
Inagi, Shinsuke
Synthesis of Cationic Azatriphenylene Derivatives by Electrochemical Intramolecular Pyridination and Characterization of Their Optoelectronic Properties
title Synthesis of Cationic Azatriphenylene Derivatives by Electrochemical Intramolecular Pyridination and Characterization of Their Optoelectronic Properties
title_full Synthesis of Cationic Azatriphenylene Derivatives by Electrochemical Intramolecular Pyridination and Characterization of Their Optoelectronic Properties
title_fullStr Synthesis of Cationic Azatriphenylene Derivatives by Electrochemical Intramolecular Pyridination and Characterization of Their Optoelectronic Properties
title_full_unstemmed Synthesis of Cationic Azatriphenylene Derivatives by Electrochemical Intramolecular Pyridination and Characterization of Their Optoelectronic Properties
title_short Synthesis of Cationic Azatriphenylene Derivatives by Electrochemical Intramolecular Pyridination and Characterization of Their Optoelectronic Properties
title_sort synthesis of cationic azatriphenylene derivatives by electrochemical intramolecular pyridination and characterization of their optoelectronic properties
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10243103/
https://www.ncbi.nlm.nih.gov/pubmed/37222538
http://dx.doi.org/10.1021/acs.orglett.3c01341
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