Organolithium aggregation as a blueprint to construct polynuclear lithium nickelate clusters

By exploiting the high aggregation of aliphatic lithium acetylides, here we report the synthesis and structural analysis of polynuclear lithium nickelate clusters in which up to 10 equivalents of organolithium can co-complex per Ni(0) centre. Exposure of the Ni(0)-ate clusters to dry air provides an...

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Detalles Bibliográficos
Autores principales: Borys, Andryj M., Hevia, Eva
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10243118/
https://www.ncbi.nlm.nih.gov/pubmed/37191064
http://dx.doi.org/10.1039/d3cc01729j
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author Borys, Andryj M.
Hevia, Eva
author_facet Borys, Andryj M.
Hevia, Eva
author_sort Borys, Andryj M.
collection PubMed
description By exploiting the high aggregation of aliphatic lithium acetylides, here we report the synthesis and structural analysis of polynuclear lithium nickelate clusters in which up to 10 equivalents of organolithium can co-complex per Ni(0) centre. Exposure of the Ni(0)-ate clusters to dry air provides an alternative route to homoleptic Ni(ii)-ates.
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spelling pubmed-102431182023-06-07 Organolithium aggregation as a blueprint to construct polynuclear lithium nickelate clusters Borys, Andryj M. Hevia, Eva Chem Commun (Camb) Chemistry By exploiting the high aggregation of aliphatic lithium acetylides, here we report the synthesis and structural analysis of polynuclear lithium nickelate clusters in which up to 10 equivalents of organolithium can co-complex per Ni(0) centre. Exposure of the Ni(0)-ate clusters to dry air provides an alternative route to homoleptic Ni(ii)-ates. The Royal Society of Chemistry 2023-04-28 /pmc/articles/PMC10243118/ /pubmed/37191064 http://dx.doi.org/10.1039/d3cc01729j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Borys, Andryj M.
Hevia, Eva
Organolithium aggregation as a blueprint to construct polynuclear lithium nickelate clusters
title Organolithium aggregation as a blueprint to construct polynuclear lithium nickelate clusters
title_full Organolithium aggregation as a blueprint to construct polynuclear lithium nickelate clusters
title_fullStr Organolithium aggregation as a blueprint to construct polynuclear lithium nickelate clusters
title_full_unstemmed Organolithium aggregation as a blueprint to construct polynuclear lithium nickelate clusters
title_short Organolithium aggregation as a blueprint to construct polynuclear lithium nickelate clusters
title_sort organolithium aggregation as a blueprint to construct polynuclear lithium nickelate clusters
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10243118/
https://www.ncbi.nlm.nih.gov/pubmed/37191064
http://dx.doi.org/10.1039/d3cc01729j
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