Cargando…
Stabilization of Pd NPs over the surface of β-cyclodextrin incorporated UiO-66-NH(2) for the C–C coupling reaction
Here, we prepared UiO-66-NH(2) and employed a post-synthesis modification method for its functionalization with a β-cyclodextrin (β-CD) organic compound. The resulting composite was employed as a support for the heterogenization of the Pd NPs. Various techniques, including FT-IR, XRD, SEM, TEM, EDS,...
Autores principales: | , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10246555/ https://www.ncbi.nlm.nih.gov/pubmed/37293468 http://dx.doi.org/10.1039/d2ra08347g |
Sumario: | Here, we prepared UiO-66-NH(2) and employed a post-synthesis modification method for its functionalization with a β-cyclodextrin (β-CD) organic compound. The resulting composite was employed as a support for the heterogenization of the Pd NPs. Various techniques, including FT-IR, XRD, SEM, TEM, EDS, and elemental mapping, were used to characterize UiO-66-NH(2)@β-CD/Pd(NPs), indicating its successful preparation. Three C–C coupling reactions, including the Suzuki, Heck, and Sonogashira coupling reactions, were promoted using the produced catalyst. As a result of the PSM, the proposed catalyst displays improved catalytic performance. In addition, the suggested catalyst was highly recyclable up to 6 times. |
---|