Cargando…

Distal meta-C–H functionalization of α-substituted cinnamates

Development of a novel strategy for the palladium-catalyzed selective meta-C–H activation of α-substituted cinnamates and their heterocyclic analogues with various alkenes using nitrile as a directing group (DG) has been described. Importantly, we introduced naphthoquinone, benzoquinones, maleimides...

Descripción completa

Detalles Bibliográficos
Autores principales:	Bakthadoss, Manickam, Reddy, Tadiparthi Thirupathi
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2023
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10246684/ https://www.ncbi.nlm.nih.gov/pubmed/37293646 http://dx.doi.org/10.1039/d2sc06206b

Ejemplares similares

Ruthenium-catalyzed, site-selective C–H activation: access to C5-substituted azaflavanone
por: Bakthadoss, Manickam, et al.
Publicado: (2020)

A distal vinyl shift (DVS) through quadruple domino reaction: synthesis of N-vinyl benzoheterocyclic scaffolds
por: Bakthadoss, Manickam, et al.
Publicado: (2018)

Responsive Fluorescent Coumarin–Cinnamic Acid Conjugates for α-Glucosidase Detection
por: Luo, Dong, et al.
Publicado: (2022)

Cascade annulation reaction (CAR): highly diastereoselective synthesis of pyranopyrazole scaffolds
por: Bakthadoss, Manickam, et al.
Publicado: (2020)

2-Formyl-6-methoxyphenyl cinnamate
por: Manikandan, N., et al.
Publicado: (2012)

Temperature-modulated selective C(sp(3))–H or C(sp(2))–H arylation through palladium catalysis
por: Gogula, Thirupathi, et al.
Publicado: (2020)

Construction of multi-substituted pyrazoles via potassium carbonate-mediated [3 + 2] cycloaddition of in situ generated nitrile imines with cinnamic aldehydes
por: Li, Mei-Mei, et al.
Publicado: (2022)

Two step, one-pot sequential synthesis of functionalized hybrid polyheterocyclic scaffolds via a solid state melt reaction (SSMR)
por: Bakthadoss, Manickam, et al.
Publicado: (2019)

pH and light dual stimuli-responses of mixed system of 2-hydroxyl-propanediyl-α,ω-bis(dimethyldodecyl ammonium bromide) and trans-ortho-hydroxyl cinnamic acid
por: Liu, Wenxiu, et al.
Publicado: (2022)

Novozym 40086 as a novel biocatalyst to improve benzyl cinnamate synthesis
por: Sun, Shangde, et al.
Publicado: (2018)

Diverse strategies for transition metal catalyzed distal C(sp(3))–H functionalizations
por: Das, Jayabrata, et al.
Publicado: (2020)

Electron-beam lithography of cinnamate polythiophene films: conductive nanorods for electronic applications
por: Bojanowski, N. Maximilian, et al.
Publicado: (2022)

A general method for the metal-free, regioselective, remote C–H halogenation of 8-substituted quinolines
por: Motati, Damoder Reddy, et al.
Publicado: (2018)

Insights into the role of noncovalent interactions in distal functionalization of the aryl C(sp(2))–H bond
por: Unnikrishnan, Anju, et al.
Publicado: (2019)

Primary α-tertiary amine synthesis via α-C–H functionalization
por: Vasu, Dhananjayan, et al.
Publicado: (2019)

Impact of B-Ring Substitution and Acylation with Hydroxy Cinnamic Acids on the Inhibition of Porcine α-Amylase by Anthocyanin-3-Glycosides
por: Kaeswurm, Julia A. H., et al.
Publicado: (2020)

Correction: design, synthesis and evaluation of cinnamic acid ester derivatives as mushroom tyrosinase inhibitors
por: Sheng, Zhaojun, et al.
Publicado: (2018)

Synthesis and biological evaluation of phosphatidylcholines with cinnamic and 3-methoxycinnamic acids with potent antiproliferative activity
por: Czarnecka, Marta, et al.
Publicado: (2018)

Creatininium cinnamate
por: Ali, A. Jahubar, et al.
Publicado: (2011)

Robust, site-specifically immobilized phenylalanine ammonia-lyases for the enantioselective ammonia addition of cinnamic acids
por: Boros, Krisztina, et al.
Publicado: (2021)

Rhodium catalyzed template-assisted distal para-C–H olefination
por: Dutta, Uttam, et al.
Publicado: (2019)

Larvicidal and histopathological efficacy of cinnamic acid analogues: a novel strategy to reduce the dengue vector competence
por: Naresh, P., et al.
Publicado: (2022)

Ligand and counteranion enabled regiodivergent C–H bond functionalization of naphthols with α-aryl-α-diazoesters
por: Yu, Zhunzhun, et al.
Publicado: (2019)

Highly sensitive turn-off fluorescent detection of cyanide in aqueous medium using dicyanovinyl-substituted phenanthridine fluorophore
por: Manickam, Saravanakumar, et al.
Publicado: (2020)

Design, Synthesis and Anticancer Evaluation of Substituted Cinnamic Acid Bearing 2-Quinolone Hybrid Derivatives
por: Abu Almaaty, Ali H., et al.
Publicado: (2021)

1-Methyl-3-p-tolyl-3,3a,4,9b-tetrahydro-1H-chromeno[4,3-c]isoxazole-3a-carbonitrile
por: Gangadharan, Rajeswari, et al.
Publicado: (2011)

Poly(styrene-ran-cinnamic acid) (SCA), an approach to modified polystyrene with enhanced impact toughness, heat resistance and melt strength
por: Wang, Jie, et al.
Publicado: (2019)

C–H activation and nucleophilic substitution in a photochemically generated high valent iron complex
por: Lim, Jia Hui, et al.
Publicado: (2018)

The Ag-promoted α-C–H arylation of alcohols
por: Wang, Shoufeng, et al.
Publicado: (2019)

Cinnamate-based DNA photolithography
por: Feng, Lang, et al.
Publicado: (2013)

Multifunctional Cinnamic Acid Derivatives
por: Peperidou, Aikaterini, et al.
Publicado: (2017)

Ortho-aryl substituted DPEphos ligands: rhodium complexes featuring C–H anagostic interactions and B–H agostic bonds
por: Race, James J., et al.
Publicado: (2021)

1-Methyl-3-(naphthalen-1-yl)-3,3a,4,9b-tetrahydro-1H-chromeno[4,3-c]isoxazole-3a-carbonitrile
por: Gangadharan, Rajeswari, et al.
Publicado: (2011)

Novel synthesis of 1,2-diaza-1,3-dienes with potential biological activity from cinnamic acids and diazonium salts of anilines
por: Vida, Veronica, et al.
Publicado: (2022)

Phosphine-catalyzed [3 + 2] annulation of β-sulfonamido-substituted enones with trans-α-cyano-α,β-unsaturated ketones for the synthesis of highly substituted pyrrolidines
por: Gao, Zhenzhen, et al.
Publicado: (2021)

Iron-catalyzed α-C–H functionalization of π-bonds: cross-dehydrogenative coupling and mechanistic insights
por: Wang, Yidong, et al.
Publicado: (2020)

Visible-light-promoted N–H functionalization of O-substituted hydroxamic acid with diazo esters
por: Xia, Shuangshuang, et al.
Publicado: (2023)

Mechanisms for Improving Hepatic Glucolipid Metabolism by Cinnamic Acid and Cinnamic Aldehyde: An Insight Provided by Multi-Omics
por: Wu, You, et al.
Publicado: (2022)

Targeting matrix metalloproteinases with novel diazepine substituted cinnamic acid derivatives: design, synthesis, in vitro and in silico studies
por: Rathee, Dharmender, et al.
Publicado: (2018)

Anticonvulsant Activity of Halogen-Substituted Cinnamic Acid Derivatives and Their Effects on Glycosylation of PTZ-Induced Chronic Epilepsy in Mice
por: Cuan, Ye, et al.
Publicado: (2017)

Cannot write session to /tmp/vufind_sessions/sess_9rf81c1lkg00a9hskqcoouec3m