Chemical and Physical Properties of YHg(3) and LuHg(3)

[Image: see text] Amalgams have played an important role in fundamental and applied solid-state chemistry and physics because of the diversity of crystallographic features and properties that they have to offer. Moreover, their peculiar chemical properties can sometimes give rise to unconventional s...

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Autores principales: Witthaut, Kristian, Prots, Yurii, Zaremba, Nazar, Krnel, Mitja, Leithe-Jasper, Andreas, Grin, Yuri, Svanidze, Eteri
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10251501/
https://www.ncbi.nlm.nih.gov/pubmed/37303500
http://dx.doi.org/10.1021/acsorginorgau.2c00048
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author Witthaut, Kristian
Prots, Yurii
Zaremba, Nazar
Krnel, Mitja
Leithe-Jasper, Andreas
Grin, Yuri
Svanidze, Eteri
author_facet Witthaut, Kristian
Prots, Yurii
Zaremba, Nazar
Krnel, Mitja
Leithe-Jasper, Andreas
Grin, Yuri
Svanidze, Eteri
author_sort Witthaut, Kristian
collection PubMed
description [Image: see text] Amalgams have played an important role in fundamental and applied solid-state chemistry and physics because of the diversity of crystallographic features and properties that they have to offer. Moreover, their peculiar chemical properties can sometimes give rise to unconventional superconducting or magnetic ground states. In the current work, we present an in-depth analysis of single crystals of YHg(3) and LuHg(3) (Mg(3)Cd structure type, space group P6(3)/mmc). Both compounds show superconductivity below T(c) = 1 ± 0.1 K (YHg(3)) and T(c) = 1.2 ± 0.1 K (LuHg(3)). Given the high air-sensitivity and toxicity of these compounds, this study was only possible using a number of dedicated experimental techniques.
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spelling pubmed-102515012023-06-10 Chemical and Physical Properties of YHg(3) and LuHg(3) Witthaut, Kristian Prots, Yurii Zaremba, Nazar Krnel, Mitja Leithe-Jasper, Andreas Grin, Yuri Svanidze, Eteri ACS Org Inorg Au [Image: see text] Amalgams have played an important role in fundamental and applied solid-state chemistry and physics because of the diversity of crystallographic features and properties that they have to offer. Moreover, their peculiar chemical properties can sometimes give rise to unconventional superconducting or magnetic ground states. In the current work, we present an in-depth analysis of single crystals of YHg(3) and LuHg(3) (Mg(3)Cd structure type, space group P6(3)/mmc). Both compounds show superconductivity below T(c) = 1 ± 0.1 K (YHg(3)) and T(c) = 1.2 ± 0.1 K (LuHg(3)). Given the high air-sensitivity and toxicity of these compounds, this study was only possible using a number of dedicated experimental techniques. American Chemical Society 2023-02-02 /pmc/articles/PMC10251501/ /pubmed/37303500 http://dx.doi.org/10.1021/acsorginorgau.2c00048 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Witthaut, Kristian
Prots, Yurii
Zaremba, Nazar
Krnel, Mitja
Leithe-Jasper, Andreas
Grin, Yuri
Svanidze, Eteri
Chemical and Physical Properties of YHg(3) and LuHg(3)
title Chemical and Physical Properties of YHg(3) and LuHg(3)
title_full Chemical and Physical Properties of YHg(3) and LuHg(3)
title_fullStr Chemical and Physical Properties of YHg(3) and LuHg(3)
title_full_unstemmed Chemical and Physical Properties of YHg(3) and LuHg(3)
title_short Chemical and Physical Properties of YHg(3) and LuHg(3)
title_sort chemical and physical properties of yhg(3) and luhg(3)
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10251501/
https://www.ncbi.nlm.nih.gov/pubmed/37303500
http://dx.doi.org/10.1021/acsorginorgau.2c00048
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