Highly Rotationally Excited N(2) Reveals Transition-State Character in the Thermal Decomposition of N(2)O on Pd(110)

[Image: see text] We employ time-slice and velocity map ion imaging methods to explore the quantum-state resolved dynamics in thermal N(2)O decomposition on Pd(110). We observe two reaction channels: a thermal channel that is ascribed to N(2) products initially trapped at surface defects and a hyper...

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Detalles Bibliográficos
Autores principales: Quan, Jiamei, Yin, Rongrong, Zhao, Zibo, Yang, Ximei, Kandratsenka, Alexander, Auerbach, Daniel J., Wodtke, Alec M., Guo, Hua, Park, G. Barratt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10251513/
https://www.ncbi.nlm.nih.gov/pubmed/37226051
http://dx.doi.org/10.1021/jacs.3c01127

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