Improving the Wear-Resistance of BT22 Titanium Alloy by Forming Nano-Cellular Topography via Laser-Thermochemical Processing

This paper studies the microstructure, phase composition and tribological response of BT22 bimodal titanium alloy samples, which were selectively laser-processed before nitriding. Laser power was selected to obtain a maximum temperature just a little above the α↔β transus point. This allows for the formation of a nano-fine cell-type microstructure. The average grain size of the nitrided layer obtained in this study was 300–400 nm, and 30–100 nm for some smaller cells. The width of the “microchannels” between some of them was 2–5 nm. This microstructure was detected on both the intact surface and the wear track. XRD tests proved the prevailing formation of Ti(2)N. The thickness of the nitride layer was 15–20 μm between the laser spots, and 50 μm below them, with a maximum surface hardness of 1190 HV(0.01). Microstructure analyses revealed nitrogen diffusion along the grain boundaries. Tribological studies were performed using a PoD tribometer in dry sliding conditions, with a counterpart fabricated from untreated titanium alloy BT22. The comparative wear test indicates the superiority of the laser+nitrided alloy over the one that was only nitrided: the weight loss was 28% lower, with a 16% decrease in the coefficient of friction. The predominant wear mechanism of the nitrided sample was determined to be micro-abrasive wear accompanied by delamination, while that of the laser+nitrided sample was micro-abrasive wear. The cellular microstructure of the nitrided layer obtained after the combined laser-thermochemical processing helps to withstand substrate deformations and provide better wear-resistance.