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Effects of Surface Properties of Fiber on Interface Properties of Carbon Fiber/Epoxy Resin and Its Graphene Oxide Modified Hybrid Composites
In the present study, surface properties of three types of carbon fibers (CCF300, CCM40J, and CCF800H) on the interface properties of carbon fiber/epoxy resin (CF/EP) were analyzed. The composites are further modified by graphene oxide (GO) to obtain GO/CF/EP hybrid composites. Meanwhile, the effect...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254778/ https://www.ncbi.nlm.nih.gov/pubmed/37297138 http://dx.doi.org/10.3390/ma16114005 |
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author | Bai, Weihua Liu, Wenjun Li, Weidong Lin, Zewen Qiu, Hong Hu, Xiaolan |
author_facet | Bai, Weihua Liu, Wenjun Li, Weidong Lin, Zewen Qiu, Hong Hu, Xiaolan |
author_sort | Bai, Weihua |
collection | PubMed |
description | In the present study, surface properties of three types of carbon fibers (CCF300, CCM40J, and CCF800H) on the interface properties of carbon fiber/epoxy resin (CF/EP) were analyzed. The composites are further modified by graphene oxide (GO) to obtain GO/CF/EP hybrid composites. Meanwhile, the effect of the surface properties of CFs and the additive graphene oxide on the interlaminar shear properties and dynamic thermomechanical properties of GO/CF/EP hybrid composites are also analyzed. The results show that the higher surface oxygen-carbon ratio of carbon fiber (CCF300) has a positive effect on improving the glass transition temperature (T(g)) of the CF/EP composites. The T(g) of CCF300/EP is 184.4 °C, while the T(g) of CCM40J/EP and CCF800/EP are only 177.1 °C and 177.4 °C, respectively. Furthermore, deeper and more dense grooves on the fiber surface (CCF800H and CCM40J) are more conducive to improving the interlaminar shear performance of the CF/EP composites. The interlaminar shear strength (ILSS) of CCF300/EP is 59.7 MPa, and that of CCM40J/EP and CCF800H/EP are 80.1 MPa and 83.5 MPa, respectively. For the GO/CF/EP hybrid composites, graphene oxide with abundant oxygen-containing groups is beneficial to improve the interfacial interaction. Graphene oxide can significantly improve the glass transition temperature and interlamellar shear strength of GO/CCF300/EP composites fabricated by CCF300 with a higher surface oxygen-carbon ratio. For the CCM40J and CCF800H with lower surface oxygen-carbon ratio, graphene oxide has a better modification effect on the glass transition temperature and interlamellar shear strength of GO/CCM40J/EP composites fabricated by CCM40J with deeper and finer surface grooves. Regardless of the type of carbon fiber, the GO/CF/EP hybrid composites with 0.1% graphene oxide have the optimized interlaminar shear strength, and the GO/CF/EP hybrid composites with 0.5% graphene oxide have the maximum glass transition temperature. |
format | Online Article Text |
id | pubmed-10254778 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-102547782023-06-10 Effects of Surface Properties of Fiber on Interface Properties of Carbon Fiber/Epoxy Resin and Its Graphene Oxide Modified Hybrid Composites Bai, Weihua Liu, Wenjun Li, Weidong Lin, Zewen Qiu, Hong Hu, Xiaolan Materials (Basel) Article In the present study, surface properties of three types of carbon fibers (CCF300, CCM40J, and CCF800H) on the interface properties of carbon fiber/epoxy resin (CF/EP) were analyzed. The composites are further modified by graphene oxide (GO) to obtain GO/CF/EP hybrid composites. Meanwhile, the effect of the surface properties of CFs and the additive graphene oxide on the interlaminar shear properties and dynamic thermomechanical properties of GO/CF/EP hybrid composites are also analyzed. The results show that the higher surface oxygen-carbon ratio of carbon fiber (CCF300) has a positive effect on improving the glass transition temperature (T(g)) of the CF/EP composites. The T(g) of CCF300/EP is 184.4 °C, while the T(g) of CCM40J/EP and CCF800/EP are only 177.1 °C and 177.4 °C, respectively. Furthermore, deeper and more dense grooves on the fiber surface (CCF800H and CCM40J) are more conducive to improving the interlaminar shear performance of the CF/EP composites. The interlaminar shear strength (ILSS) of CCF300/EP is 59.7 MPa, and that of CCM40J/EP and CCF800H/EP are 80.1 MPa and 83.5 MPa, respectively. For the GO/CF/EP hybrid composites, graphene oxide with abundant oxygen-containing groups is beneficial to improve the interfacial interaction. Graphene oxide can significantly improve the glass transition temperature and interlamellar shear strength of GO/CCF300/EP composites fabricated by CCF300 with a higher surface oxygen-carbon ratio. For the CCM40J and CCF800H with lower surface oxygen-carbon ratio, graphene oxide has a better modification effect on the glass transition temperature and interlamellar shear strength of GO/CCM40J/EP composites fabricated by CCM40J with deeper and finer surface grooves. Regardless of the type of carbon fiber, the GO/CF/EP hybrid composites with 0.1% graphene oxide have the optimized interlaminar shear strength, and the GO/CF/EP hybrid composites with 0.5% graphene oxide have the maximum glass transition temperature. MDPI 2023-05-26 /pmc/articles/PMC10254778/ /pubmed/37297138 http://dx.doi.org/10.3390/ma16114005 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Bai, Weihua Liu, Wenjun Li, Weidong Lin, Zewen Qiu, Hong Hu, Xiaolan Effects of Surface Properties of Fiber on Interface Properties of Carbon Fiber/Epoxy Resin and Its Graphene Oxide Modified Hybrid Composites |
title | Effects of Surface Properties of Fiber on Interface Properties of Carbon Fiber/Epoxy Resin and Its Graphene Oxide Modified Hybrid Composites |
title_full | Effects of Surface Properties of Fiber on Interface Properties of Carbon Fiber/Epoxy Resin and Its Graphene Oxide Modified Hybrid Composites |
title_fullStr | Effects of Surface Properties of Fiber on Interface Properties of Carbon Fiber/Epoxy Resin and Its Graphene Oxide Modified Hybrid Composites |
title_full_unstemmed | Effects of Surface Properties of Fiber on Interface Properties of Carbon Fiber/Epoxy Resin and Its Graphene Oxide Modified Hybrid Composites |
title_short | Effects of Surface Properties of Fiber on Interface Properties of Carbon Fiber/Epoxy Resin and Its Graphene Oxide Modified Hybrid Composites |
title_sort | effects of surface properties of fiber on interface properties of carbon fiber/epoxy resin and its graphene oxide modified hybrid composites |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10254778/ https://www.ncbi.nlm.nih.gov/pubmed/37297138 http://dx.doi.org/10.3390/ma16114005 |
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