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Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir

[Image: see text] Closed shell molecular structures are under normal conditions time-reversal invariant. Experimental evidence points, however, toward that this invariance may be locally violated when the structure is in contact with a particle reservoir. The mechanisms behind such local symmetry br...

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Detalles Bibliográficos
Autores principales: Shiranzaei, M., Kalhöfer, S., Fransson, J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10258847/
https://www.ncbi.nlm.nih.gov/pubmed/37249543
http://dx.doi.org/10.1021/acs.jpclett.3c00526
Descripción
Sumario:[Image: see text] Closed shell molecular structures are under normal conditions time-reversal invariant. Experimental evidence points, however, toward that this invariance may be locally violated when the structure is in contact with a particle reservoir. The mechanisms behind such local symmetry breaking are not clear by any means. By considering a minimal model for a closed shell structure, here we propose that the symmetry breaking may result from a combination of internal and/or external interactions. It is shown that a magnetic moment of a localized electron level can be generated and maintained under the influence of such a combination. The theoretical results should cast new light on the mechanisms that may form magnetic properties in molecular compounds.