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Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir
[Image: see text] Closed shell molecular structures are under normal conditions time-reversal invariant. Experimental evidence points, however, toward that this invariance may be locally violated when the structure is in contact with a particle reservoir. The mechanisms behind such local symmetry br...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10258847/ https://www.ncbi.nlm.nih.gov/pubmed/37249543 http://dx.doi.org/10.1021/acs.jpclett.3c00526 |
Sumario: | [Image: see text] Closed shell molecular structures are under normal conditions time-reversal invariant. Experimental evidence points, however, toward that this invariance may be locally violated when the structure is in contact with a particle reservoir. The mechanisms behind such local symmetry breaking are not clear by any means. By considering a minimal model for a closed shell structure, here we propose that the symmetry breaking may result from a combination of internal and/or external interactions. It is shown that a magnetic moment of a localized electron level can be generated and maintained under the influence of such a combination. The theoretical results should cast new light on the mechanisms that may form magnetic properties in molecular compounds. |
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