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Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir
[Image: see text] Closed shell molecular structures are under normal conditions time-reversal invariant. Experimental evidence points, however, toward that this invariance may be locally violated when the structure is in contact with a particle reservoir. The mechanisms behind such local symmetry br...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10258847/ https://www.ncbi.nlm.nih.gov/pubmed/37249543 http://dx.doi.org/10.1021/acs.jpclett.3c00526 |
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author | Shiranzaei, M. Kalhöfer, S. Fransson, J. |
author_facet | Shiranzaei, M. Kalhöfer, S. Fransson, J. |
author_sort | Shiranzaei, M. |
collection | PubMed |
description | [Image: see text] Closed shell molecular structures are under normal conditions time-reversal invariant. Experimental evidence points, however, toward that this invariance may be locally violated when the structure is in contact with a particle reservoir. The mechanisms behind such local symmetry breaking are not clear by any means. By considering a minimal model for a closed shell structure, here we propose that the symmetry breaking may result from a combination of internal and/or external interactions. It is shown that a magnetic moment of a localized electron level can be generated and maintained under the influence of such a combination. The theoretical results should cast new light on the mechanisms that may form magnetic properties in molecular compounds. |
format | Online Article Text |
id | pubmed-10258847 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-102588472023-06-13 Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir Shiranzaei, M. Kalhöfer, S. Fransson, J. J Phys Chem Lett [Image: see text] Closed shell molecular structures are under normal conditions time-reversal invariant. Experimental evidence points, however, toward that this invariance may be locally violated when the structure is in contact with a particle reservoir. The mechanisms behind such local symmetry breaking are not clear by any means. By considering a minimal model for a closed shell structure, here we propose that the symmetry breaking may result from a combination of internal and/or external interactions. It is shown that a magnetic moment of a localized electron level can be generated and maintained under the influence of such a combination. The theoretical results should cast new light on the mechanisms that may form magnetic properties in molecular compounds. American Chemical Society 2023-05-30 /pmc/articles/PMC10258847/ /pubmed/37249543 http://dx.doi.org/10.1021/acs.jpclett.3c00526 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Shiranzaei, M. Kalhöfer, S. Fransson, J. Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir |
title | Emergent Magnetism as a Cooperative Effect of Interactions
and Reservoir |
title_full | Emergent Magnetism as a Cooperative Effect of Interactions
and Reservoir |
title_fullStr | Emergent Magnetism as a Cooperative Effect of Interactions
and Reservoir |
title_full_unstemmed | Emergent Magnetism as a Cooperative Effect of Interactions
and Reservoir |
title_short | Emergent Magnetism as a Cooperative Effect of Interactions
and Reservoir |
title_sort | emergent magnetism as a cooperative effect of interactions
and reservoir |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10258847/ https://www.ncbi.nlm.nih.gov/pubmed/37249543 http://dx.doi.org/10.1021/acs.jpclett.3c00526 |
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