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Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir

[Image: see text] Closed shell molecular structures are under normal conditions time-reversal invariant. Experimental evidence points, however, toward that this invariance may be locally violated when the structure is in contact with a particle reservoir. The mechanisms behind such local symmetry br...

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Autores principales: Shiranzaei, M., Kalhöfer, S., Fransson, J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10258847/
https://www.ncbi.nlm.nih.gov/pubmed/37249543
http://dx.doi.org/10.1021/acs.jpclett.3c00526
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author Shiranzaei, M.
Kalhöfer, S.
Fransson, J.
author_facet Shiranzaei, M.
Kalhöfer, S.
Fransson, J.
author_sort Shiranzaei, M.
collection PubMed
description [Image: see text] Closed shell molecular structures are under normal conditions time-reversal invariant. Experimental evidence points, however, toward that this invariance may be locally violated when the structure is in contact with a particle reservoir. The mechanisms behind such local symmetry breaking are not clear by any means. By considering a minimal model for a closed shell structure, here we propose that the symmetry breaking may result from a combination of internal and/or external interactions. It is shown that a magnetic moment of a localized electron level can be generated and maintained under the influence of such a combination. The theoretical results should cast new light on the mechanisms that may form magnetic properties in molecular compounds.
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spelling pubmed-102588472023-06-13 Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir Shiranzaei, M. Kalhöfer, S. Fransson, J. J Phys Chem Lett [Image: see text] Closed shell molecular structures are under normal conditions time-reversal invariant. Experimental evidence points, however, toward that this invariance may be locally violated when the structure is in contact with a particle reservoir. The mechanisms behind such local symmetry breaking are not clear by any means. By considering a minimal model for a closed shell structure, here we propose that the symmetry breaking may result from a combination of internal and/or external interactions. It is shown that a magnetic moment of a localized electron level can be generated and maintained under the influence of such a combination. The theoretical results should cast new light on the mechanisms that may form magnetic properties in molecular compounds. American Chemical Society 2023-05-30 /pmc/articles/PMC10258847/ /pubmed/37249543 http://dx.doi.org/10.1021/acs.jpclett.3c00526 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Shiranzaei, M.
Kalhöfer, S.
Fransson, J.
Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir
title Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir
title_full Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir
title_fullStr Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir
title_full_unstemmed Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir
title_short Emergent Magnetism as a Cooperative Effect of Interactions and Reservoir
title_sort emergent magnetism as a cooperative effect of interactions and reservoir
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10258847/
https://www.ncbi.nlm.nih.gov/pubmed/37249543
http://dx.doi.org/10.1021/acs.jpclett.3c00526
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