Tuning the Effect of Chitosan on the Electrochemical Responsiveness of Lignin Nanoparticles

[Image: see text] Chitosan and lignin mixed nanoparticles were prepared by layer-by-layer and nanoprecipitation methodologies as responsive platforms for sustainable biosensors. The novel nanoparticles showed effective chemophysical and electrochemical properties dependent on the preparation methodo...

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Autores principales: Gigli, Valeria, Capecchi, Eliana, Tortolini, Cristina, Isidori, Andrea, Antiochia, Riccarda, Saladino, Raffaele
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10265579/
https://www.ncbi.nlm.nih.gov/pubmed/37192401
http://dx.doi.org/10.1021/acsbiomaterials.2c01494
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author Gigli, Valeria
Capecchi, Eliana
Tortolini, Cristina
Isidori, Andrea
Antiochia, Riccarda
Saladino, Raffaele
author_facet Gigli, Valeria
Capecchi, Eliana
Tortolini, Cristina
Isidori, Andrea
Antiochia, Riccarda
Saladino, Raffaele
author_sort Gigli, Valeria
collection PubMed
description [Image: see text] Chitosan and lignin mixed nanoparticles were prepared by layer-by-layer and nanoprecipitation methodologies as responsive platforms for sustainable biosensors. The novel nanoparticles showed effective chemophysical and electrochemical properties dependent on the preparation methodology, molecular weight of chitosan, and type of lignin. HOMO–LUMO energy gap calculations suggested the presence of structure–activity relationships between the electrochemical responsiveness and the order and orientation of lignin aromatic subunits and chitosan chains in the nanodevices.
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spelling pubmed-102655792023-06-15 Tuning the Effect of Chitosan on the Electrochemical Responsiveness of Lignin Nanoparticles Gigli, Valeria Capecchi, Eliana Tortolini, Cristina Isidori, Andrea Antiochia, Riccarda Saladino, Raffaele ACS Biomater Sci Eng [Image: see text] Chitosan and lignin mixed nanoparticles were prepared by layer-by-layer and nanoprecipitation methodologies as responsive platforms for sustainable biosensors. The novel nanoparticles showed effective chemophysical and electrochemical properties dependent on the preparation methodology, molecular weight of chitosan, and type of lignin. HOMO–LUMO energy gap calculations suggested the presence of structure–activity relationships between the electrochemical responsiveness and the order and orientation of lignin aromatic subunits and chitosan chains in the nanodevices. American Chemical Society 2023-05-16 /pmc/articles/PMC10265579/ /pubmed/37192401 http://dx.doi.org/10.1021/acsbiomaterials.2c01494 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Gigli, Valeria
Capecchi, Eliana
Tortolini, Cristina
Isidori, Andrea
Antiochia, Riccarda
Saladino, Raffaele
Tuning the Effect of Chitosan on the Electrochemical Responsiveness of Lignin Nanoparticles
title Tuning the Effect of Chitosan on the Electrochemical Responsiveness of Lignin Nanoparticles
title_full Tuning the Effect of Chitosan on the Electrochemical Responsiveness of Lignin Nanoparticles
title_fullStr Tuning the Effect of Chitosan on the Electrochemical Responsiveness of Lignin Nanoparticles
title_full_unstemmed Tuning the Effect of Chitosan on the Electrochemical Responsiveness of Lignin Nanoparticles
title_short Tuning the Effect of Chitosan on the Electrochemical Responsiveness of Lignin Nanoparticles
title_sort tuning the effect of chitosan on the electrochemical responsiveness of lignin nanoparticles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10265579/
https://www.ncbi.nlm.nih.gov/pubmed/37192401
http://dx.doi.org/10.1021/acsbiomaterials.2c01494
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