Catalytic generation of ortho-quinone dimethides via donor/donor rhodium carbenes

Substrates engineered to undergo a 1,4-C–H insertion to yield benzocyclobutenes resulted in a novel elimination reaction to yield ortho-quinone dimethide (o-QDM) intermediates that undergo Diels–Alder or hetero-Diels–Alder cycloadditions. The analogous benzylic acetals or ethers avoid the C–H insert...

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Detalles Bibliográficos
Autores principales: Gao, Mingchun, Ruiz, Jose M., Jimenez, Emily, Lo, Anna, Laconsay, Croix J., Fettinger, James C., Tantillo, Dean J., Shaw, Jared T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266466/
https://www.ncbi.nlm.nih.gov/pubmed/37325151
http://dx.doi.org/10.1039/d3sc00734k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10266466/
https://www.ncbi.nlm.nih.gov/pubmed/37325151
http://dx.doi.org/10.1039/d3sc00734k

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