First Iridium(IV) Chloride–Dimethyl Sulfoxide Complex [H(dmso)(2)][IrCl(5)(dmso-κO)]: Synthesis and Structure along with Novel Polymorph Modifications of [H(dmso)(2)][trans-IrCl(4)(dmso-κS)(2)] and [H(dmso)][trans-IrCl(4)(dmso-κS)(2)]

[Image: see text] As evidenced by UV–Vis and EPR spectroscopies, the reaction of H(2)IrCl(6)·6H(2)O or Na(2)[IrCl(6)]·nH(2)O with DMSO results in a slow reduction of Ir(IV) avoiding the formation of Ir(IV) dimethyl sulfoxide complexes in measurable quantities. More specifically, we successfully isol...

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Detalles Bibliográficos
Autores principales: Rudnitskaya, Olga V., Tereshina, Tatiana A., Dobrokhotova, Ekaterina V., Kultyshkina, Ekaterina K., Chumakova, Natalia A., Kokorin, Alexander I., Zubavichus, Yan V., Khrustalev, Victor N.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10268271/
https://www.ncbi.nlm.nih.gov/pubmed/37323389
http://dx.doi.org/10.1021/acsomega.3c01012

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