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Room Temperature Curable Copper Nanowire-Based Transparent Heater

[Image: see text] Copper nanowires (Cu NWs) are a promising alternative to silver NWs to develop transparent conducting films (TCFs) due to their comparable electrical conductivity and relative abundance. Postsynthetic modifications of the ink and high-temperature postannealing processes for obtaini...

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Autores principales: Kumar, Darbha V. Ravi, Koshy, Aarju Mathew, Sharma, Neha, Thomas, Neethu, Swaminathan, Parasuraman
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10269267/
https://www.ncbi.nlm.nih.gov/pubmed/37332811
http://dx.doi.org/10.1021/acsomega.3c02048
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author Kumar, Darbha V. Ravi
Koshy, Aarju Mathew
Sharma, Neha
Thomas, Neethu
Swaminathan, Parasuraman
author_facet Kumar, Darbha V. Ravi
Koshy, Aarju Mathew
Sharma, Neha
Thomas, Neethu
Swaminathan, Parasuraman
author_sort Kumar, Darbha V. Ravi
collection PubMed
description [Image: see text] Copper nanowires (Cu NWs) are a promising alternative to silver NWs to develop transparent conducting films (TCFs) due to their comparable electrical conductivity and relative abundance. Postsynthetic modifications of the ink and high-temperature postannealing processes for obtaining conducting films are significant challenges that need to be addressed before commercial deployment of these materials. In this work, we have developed an annealing-free (room temperature curable) TCF with Cu NW ink that requires minimal postsynthetic modifications. Organic acid pretreated Cu NW ink is used for spin-coating to obtain a TCF with a sheet resistance of 9.4 Ω/sq. and optical transparency of 67.4% at 550 nm. For oxidation protection, the Cu NW TCF is encapsulated with polydimethylsiloxane (PDMS). The encapsulated film is tested as a transparent heater at various voltages and shows good repeatability. These results demonstrate the potential of Cu NW-based TCFs as a replacement for Ag-NW based TCFs for a variety of optoelectronic applications, such as transparent heaters, touch screens, and photovoltaics.
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spelling pubmed-102692672023-06-16 Room Temperature Curable Copper Nanowire-Based Transparent Heater Kumar, Darbha V. Ravi Koshy, Aarju Mathew Sharma, Neha Thomas, Neethu Swaminathan, Parasuraman ACS Omega [Image: see text] Copper nanowires (Cu NWs) are a promising alternative to silver NWs to develop transparent conducting films (TCFs) due to their comparable electrical conductivity and relative abundance. Postsynthetic modifications of the ink and high-temperature postannealing processes for obtaining conducting films are significant challenges that need to be addressed before commercial deployment of these materials. In this work, we have developed an annealing-free (room temperature curable) TCF with Cu NW ink that requires minimal postsynthetic modifications. Organic acid pretreated Cu NW ink is used for spin-coating to obtain a TCF with a sheet resistance of 9.4 Ω/sq. and optical transparency of 67.4% at 550 nm. For oxidation protection, the Cu NW TCF is encapsulated with polydimethylsiloxane (PDMS). The encapsulated film is tested as a transparent heater at various voltages and shows good repeatability. These results demonstrate the potential of Cu NW-based TCFs as a replacement for Ag-NW based TCFs for a variety of optoelectronic applications, such as transparent heaters, touch screens, and photovoltaics. American Chemical Society 2023-06-05 /pmc/articles/PMC10269267/ /pubmed/37332811 http://dx.doi.org/10.1021/acsomega.3c02048 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Kumar, Darbha V. Ravi
Koshy, Aarju Mathew
Sharma, Neha
Thomas, Neethu
Swaminathan, Parasuraman
Room Temperature Curable Copper Nanowire-Based Transparent Heater
title Room Temperature Curable Copper Nanowire-Based Transparent Heater
title_full Room Temperature Curable Copper Nanowire-Based Transparent Heater
title_fullStr Room Temperature Curable Copper Nanowire-Based Transparent Heater
title_full_unstemmed Room Temperature Curable Copper Nanowire-Based Transparent Heater
title_short Room Temperature Curable Copper Nanowire-Based Transparent Heater
title_sort room temperature curable copper nanowire-based transparent heater
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10269267/
https://www.ncbi.nlm.nih.gov/pubmed/37332811
http://dx.doi.org/10.1021/acsomega.3c02048
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