Photoredox-HAT Catalysis for Primary Amine α-C–H Alkylation: Mechanistic Insight with Transient Absorption Spectroscopy

[Image: see text] The synergistic use of (organo)photoredox catalysts with hydrogen-atom transfer (HAT) cocatalysts has emerged as a powerful strategy for innate C(sp(3))–H bond functionalization, particularly for C–H bonds α- to nitrogen. Azide ion (N(3)(–)) was recently identified as an effective...

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Detalles Bibliográficos
Autores principales: Sneha, Mahima, Thornton, Georgia L., Lewis-Borrell, Luke, Ryder, Alison S. H., Espley, Samuel G., Clark, Ian P., Cresswell, Alexander J., Grayson, Matthew N., Orr-Ewing, Andrew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10278065/
https://www.ncbi.nlm.nih.gov/pubmed/37342833
http://dx.doi.org/10.1021/acscatal.3c01474

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