A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker

Metal–organic frameworks (MOFs) based on high-connected nets are generally very attractive due to their combined robustness and porosity. Here, we describe the synthesis of BCN-348, a new high-connected Zr-MOF built from an 8-connected (8-c) cubic Zr-oxocluster and an 8-c organic linker. BCN-348 con...

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Detalles Bibliográficos
Autores principales: Ortín-Rubio, Borja, Perona-Bermejo, Cristina, Suárez del Pino, José A., Carmona, Francisco J., Gándara, Felipe, Navarro, Jorge A. R., Juanhuix, Judith, Imaz, Inhar, Maspoch, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10281490/
https://www.ncbi.nlm.nih.gov/pubmed/37272083
http://dx.doi.org/10.1039/d3cc01831h
Descripción
Sumario:Metal–organic frameworks (MOFs) based on high-connected nets are generally very attractive due to their combined robustness and porosity. Here, we describe the synthesis of BCN-348, a new high-connected Zr-MOF built from an 8-connected (8-c) cubic Zr-oxocluster and an 8-c organic linker. BCN-348 contains a minimal edge-transitive 3,4,8-c eps net, and combines mesoporosity with thermal and hydrolytic stability. Encouraging results from preliminary studies on its use as a catalyst for hydrolysis of a nerve-agent simulant suggest its potential as an agent for detoxification of chemical weapons and other pernicious compounds.

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