A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker

Metal–organic frameworks (MOFs) based on high-connected nets are generally very attractive due to their combined robustness and porosity. Here, we describe the synthesis of BCN-348, a new high-connected Zr-MOF built from an 8-connected (8-c) cubic Zr-oxocluster and an 8-c organic linker. BCN-348 con...

Descripción completa

Detalles Bibliográficos
Autores principales: Ortín-Rubio, Borja, Perona-Bermejo, Cristina, Suárez del Pino, José A., Carmona, Francisco J., Gándara, Felipe, Navarro, Jorge A. R., Juanhuix, Judith, Imaz, Inhar, Maspoch, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10281490/
https://www.ncbi.nlm.nih.gov/pubmed/37272083
http://dx.doi.org/10.1039/d3cc01831h
_version_ 1785061013410807808
author Ortín-Rubio, Borja
Perona-Bermejo, Cristina
Suárez del Pino, José A.
Carmona, Francisco J.
Gándara, Felipe
Navarro, Jorge A. R.
Juanhuix, Judith
Imaz, Inhar
Maspoch, Daniel
author_facet Ortín-Rubio, Borja
Perona-Bermejo, Cristina
Suárez del Pino, José A.
Carmona, Francisco J.
Gándara, Felipe
Navarro, Jorge A. R.
Juanhuix, Judith
Imaz, Inhar
Maspoch, Daniel
author_sort Ortín-Rubio, Borja
collection PubMed
description Metal–organic frameworks (MOFs) based on high-connected nets are generally very attractive due to their combined robustness and porosity. Here, we describe the synthesis of BCN-348, a new high-connected Zr-MOF built from an 8-connected (8-c) cubic Zr-oxocluster and an 8-c organic linker. BCN-348 contains a minimal edge-transitive 3,4,8-c eps net, and combines mesoporosity with thermal and hydrolytic stability. Encouraging results from preliminary studies on its use as a catalyst for hydrolysis of a nerve-agent simulant suggest its potential as an agent for detoxification of chemical weapons and other pernicious compounds.
format Online
Article
Text
id pubmed-10281490
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-102814902023-06-21 A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker Ortín-Rubio, Borja Perona-Bermejo, Cristina Suárez del Pino, José A. Carmona, Francisco J. Gándara, Felipe Navarro, Jorge A. R. Juanhuix, Judith Imaz, Inhar Maspoch, Daniel Chem Commun (Camb) Chemistry Metal–organic frameworks (MOFs) based on high-connected nets are generally very attractive due to their combined robustness and porosity. Here, we describe the synthesis of BCN-348, a new high-connected Zr-MOF built from an 8-connected (8-c) cubic Zr-oxocluster and an 8-c organic linker. BCN-348 contains a minimal edge-transitive 3,4,8-c eps net, and combines mesoporosity with thermal and hydrolytic stability. Encouraging results from preliminary studies on its use as a catalyst for hydrolysis of a nerve-agent simulant suggest its potential as an agent for detoxification of chemical weapons and other pernicious compounds. The Royal Society of Chemistry 2023-05-25 /pmc/articles/PMC10281490/ /pubmed/37272083 http://dx.doi.org/10.1039/d3cc01831h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by/3.0/
spellingShingle Chemistry
Ortín-Rubio, Borja
Perona-Bermejo, Cristina
Suárez del Pino, José A.
Carmona, Francisco J.
Gándara, Felipe
Navarro, Jorge A. R.
Juanhuix, Judith
Imaz, Inhar
Maspoch, Daniel
A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker
title A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker
title_full A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker
title_fullStr A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker
title_full_unstemmed A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker
title_short A mesoporous Zr-based metal–organic framework driven by the assembly of an octatopic linker
title_sort mesoporous zr-based metal–organic framework driven by the assembly of an octatopic linker
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10281490/
https://www.ncbi.nlm.nih.gov/pubmed/37272083
http://dx.doi.org/10.1039/d3cc01831h
work_keys_str_mv AT ortinrubioborja amesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT peronabermejocristina amesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT suarezdelpinojosea amesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT carmonafranciscoj amesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT gandarafelipe amesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT navarrojorgear amesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT juanhuixjudith amesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT imazinhar amesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT maspochdaniel amesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT ortinrubioborja mesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT peronabermejocristina mesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT suarezdelpinojosea mesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT carmonafranciscoj mesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT gandarafelipe mesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT navarrojorgear mesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT juanhuixjudith mesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT imazinhar mesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker
AT maspochdaniel mesoporouszrbasedmetalorganicframeworkdrivenbytheassemblyofanoctatopiclinker

Ejemplares similares