Cargando…

Bayesian-optimization-assisted discovery of stereoselective aluminum complexes for ring-opening polymerization of racemic lactide

Stereoselective ring-opening polymerization catalysts are used to produce degradable stereoregular poly(lactic acids) with thermal and mechanical properties that are superior to those of atactic polymers. However, the process of discovering highly stereoselective catalysts is still largely empirical...

Descripción completa

Detalles Bibliográficos
Autores principales:	Wang, Xiaoqian, Huang, Yang, Xie, Xiaoyu, Liu, Yan, Huo, Ziyu, Lin, Maverick, Xin, Hongliang, Tong, Rong
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10282063/ https://www.ncbi.nlm.nih.gov/pubmed/37339991 http://dx.doi.org/10.1038/s41467-023-39405-5

Ejemplares similares

Ring-Opening Polymerization of rac-Lactide with Aluminum Chiral Anilido-Oxazolinate Complexes
por: Bian, Shi, et al.
Publicado: (2014)

Mechanistic Insight into the Ring-Opening Polymerization of ε-Caprolactone and L-Lactide Using Ketiminate-Ligated Aluminum Catalysts
por: Lin, Ya-Fan, et al.
Publicado: (2019)

Stereoselective photoredox ring-opening polymerization of O-carboxyanhydrides
por: Feng, Quanyou, et al.
Publicado: (2018)

Recent advances in enantioselective ring-opening polymerization and copolymerization
por: Xie, Xiaoyu, et al.
Publicado: (2023)

Zinc-Catalyzed Highly Isoselective Ring Opening Polymerization of rac-Lactide
por: Abbina, Srinivas, et al.
Publicado: (2014)

Macromolecular Dyes by Chromophore-Initiated Ring Opening Polymerization of L-Lactide
por: Cicogna, Francesca, et al.
Publicado: (2020)

N-Heterocyclic carbene iron complexes catalyze the ring-opening polymerization of lactide
por: Nylund, Pamela V. S., et al.
Publicado: (2022)

Aluminum Salen Complexes Modified with Unsaturated Alcohol: Synthesis, Characterization, and Their Activity towards Ring-Opening Polymerization of ε-Caprolactone and D,L-Lactide
por: Zaitsev, Kirill V., et al.
Publicado: (2023)

Immortal Ring-Opening Polymerization of rac-Lactide Using Polymeric Alcohol as Initiator to Prepare Graft Copolymer
por: Liu, Na, et al.
Publicado: (2016)

Stereoselective polymerization of methyl methacrylate and rac-lactide mediated by iminomethylpyridine based Cu(ii) complexes
por: Lee, Jaegyeong, et al.
Publicado: (2020)

Ring-Opening Polymerization of L-Lactide Catalyzed by Potassium-Based Complexes: Mechanistic Studies
por: Rentero, Christian, et al.
Publicado: (2022)

Development of Heterobimetallic Al/Mg Complexes for the Very Rapid Ring-Opening Polymerization of Lactides
por: Navarro, Marta, et al.
Publicado: (2023)

Heterolepic β‐Ketoiminate Zinc Phenoxide Complexes as Efficient Catalysts for the Ring Opening Polymerization of Lactide
por: Ghosh, Swarup, et al.
Publicado: (2019)

The Effect of Solvent Hydrophilicity on the Enzymatic Ring-Opening Polymerization of L-Lactide by Candida rugosa Lipase
por: Curie, Catia Angli, et al.
Publicado: (2022)

Model Predictive Control with Integrated Model Reduction for a Continuous Lactide Ring-Opening Polymerization Process
por: Afsi, Nawel, et al.
Publicado: (2022)

Controlled organocatalyzed d,l-lactide ring-opening polymerizations: synthesis of low molecular weight oligomers
por: Newman, M. R., et al.
Publicado: (2018)

Isoselective Polymerization of rac‐Lactide by Aluminum Complexes of N‐Heterocyclic Carbene‐Phosphinidene Adducts
por: Bhattacharjee, Jayeeta, et al.
Publicado: (2021)

Chiral 1,5,7-triazabicyclo[4.4.0]dec-5-ene (TBD)-Catalyzed Stereoselective Ring-Opening Polymerization of rac-Lactide: High Reactivity for Isotactic Enriched Polylactides (PLAs)
por: Mahmood, Qaiser, et al.
Publicado: (2020)

Stereoselective biotransformation of racemic mandelic acid using immobilized laccase and (S)-mandelate dehydrogenase
por: Chen, Xing, et al.
Publicado: (2017)

Quantitative Prediction of Rate Constants for Aqueous Racemization To Avoid Pointless Stereoselective Syntheses
por: Ballard, Andrew, et al.
Publicado: (2017)

Electrochemical carbon–carbon coupling with enhanced activity and racemate stereoselectivity by microenvironment regulation
por: Kong, Kejian, et al.
Publicado: (2023)

Zinc Complexes Containing Coumarin-Derived Anilido-Aldimine Ligands as Catalysts for Ring Opening Polymerization of l-Lactide
por: Chen, Chi-Tien, et al.
Publicado: (2015)

Synthesis and Characterization of N,N,O-Tridentate Aminophenolate Zinc Complexes and Their Catalysis in the Ring-Opening Polymerization of Lactides
por: Lu, Wei-Yi, et al.
Publicado: (2019)

Towards New Robust Zn(II) Complexes for the Ring‐Opening Polymerization of Lactide Under Industrially Relevant Conditions
por: Schäfer, Pascal M., et al.
Publicado: (2019)

In Situ Ring-Opening Polymerization of L-lactide on the Surface of Pristine and Aminated Silica: Synthesis and Metal Ions Extraction
por: Polishchuk, Liliia M., et al.
Publicado: (2022)

Copper(II) complexes with imino phenoxide ligands: synthesis, characterization, and their application as catalysts for the ring-opening polymerization of rac-lactide
por: Mandal, Mrinmay, et al.
Publicado: (2016)

Palladium complexes containing imino phenoxide ligands: synthesis, luminescence, and their use as catalysts for the ring-opening polymerization of rac-lactide
por: Mandal, Mrinmay, et al.
Publicado: (2017)

Efficient Diethylzinc/Gallic Acid and Diethylzinc/Gallic Acid Ester Catalytic Systems for the Ring-Opening Polymerization of rac-Lactide
por: Żółtowska, Karolina, et al.
Publicado: (2015)

Amides as Non-polymerizable Catalytic Adjuncts Enable the Ring-Opening Polymerization of Lactide With Ferrous Acetate Under Mild Conditions
por: Naolou, Toufik, et al.
Publicado: (2019)

Towards a selective synthetic route for cobalt amino acid complexes and their application in ring opening polymerization of rac-lactide
por: Ruiz, Andrés Castro, et al.
Publicado: (2021)

Stereoselective Ring-Opening (Co)polymerization of β-Butyrolactone and ε-Decalactone Using an Yttrium Bis(phenolate) Catalytic System
por: Kiriratnikom, Jiraya, et al.
Publicado: (2019)

Divergent Catalytic Strategies for the Cis/Trans Stereoselective Ring-Opening Polymerization of a Dual Cyclic Carbonate/Olefin Monomer
por: McGuire, Thomas M., et al.
Publicado: (2019)

Novel Poly(Methylenelactide-g-L-Lactide) Graft Copolymers Synthesized by a Combination of Vinyl Addition and Ring-Opening Polymerizations
por: Mekpothi, Tanyaluck, et al.
Publicado: (2021)

Ring opening polymerization of d,l-lactide and ε-caprolactone catalysed by (pyrazol-1-yl)copper(ii) carboxylate complexes
por: Appavoo, Divambal, et al.
Publicado: (2021)

Efficient Bulky Organo-Zinc Scorpionates for the Stereoselective Production of Poly(rac-lactide)s
por: Navarro, Marta, et al.
Publicado: (2021)

Isoselective Lactide Ring Opening Polymerisation using [2]Rotaxane Catalysts
por: Lim, Jason Y. C., et al.
Publicado: (2019)

Stereoselective methadone disposition after administration of racemic methadone to anesthetized Shetland ponies assessed by capillary electrophoresis
por: Sandbaumhüter, Friederike A., et al.
Publicado: (2021)

Enhanced Reactivity of Aluminum Complexes Containing P-Bridged Biphenolate Ligands in Ring-Opening Polymerization Catalysis
por: Zou, Xue-Ru, et al.
Publicado: (2018)

Facile Preparation of Stereoblock PLA From Ring-Opening Polymerization of rac-Lactide by a Synergetic Binary Catalytic System Containing Ureas and Alkoxides
por: Kan, Ze, et al.
Publicado: (2018)

Ring-opening polymerization-induced crystallization-driven self-assembly of poly-L-lactide-block-polyethylene glycol block copolymers (ROPI-CDSA)
por: Hurst, Paul J., et al.
Publicado: (2020)

Cannot write session to /tmp/vufind_sessions/sess_rmp91qh9ic77g3ud8e55gehc0f